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138736-91-1

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  • (1S,2R)-3,3-Dimethoxy-1,2-cyclobutanedicarboxylic Acid Di-L-Menthyl Ester

    Cas No: 138736-91-1

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138736-91-1 Usage

Chemical Properties

White Solid

Check Digit Verification of cas no

The CAS Registry Mumber 138736-91-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,8,7,3 and 6 respectively; the second part has 2 digits, 9 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 138736-91:
(8*1)+(7*3)+(6*8)+(5*7)+(4*3)+(3*6)+(2*9)+(1*1)=161
161 % 10 = 1
So 138736-91-1 is a valid CAS Registry Number.

138736-91-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (1S,2R)-3,3-Dimethoxy-1,2-cyclobutanedicarboxylic Acid Di-L-Menthyl Ester

1.2 Other means of identification

Product number -
Other names bis[(1R,2S,5R)-5-methyl-2-propan-2-ylcyclohexyl] (1R,2S)-3,3-dimethoxycyclobutane-1,2-dicarboxylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:138736-91-1 SDS

138736-91-1Relevant articles and documents

Synthesis of a new chiral bisphosphine ligand, MOCBP, and its use in rhodium(I)-catalyzed asymmetric hydrogenation of a cyclic enamide

Morimoto,Nakajima,Achiwa

, p. 75 - 78 (1995)

A new chiral bisphosphine ligand (6) bearing a cyclobutane framework was readily prepared by using diastereoselective [2 + 2] cycloaddition. Its rhodium(I) complex was found to be an efficient catalyst for the asymmetric hydrogenation of a cyclic enamide, N-acetyl-1-methylene-1,2,3,4-tetrahydroisoquinoline (9), affording (R)-(-)-N-acetylsalsolidine (10) in up to 80.6% ee.

A practical asymmetric synthesis of the antiviral agent lobucavir, BMS-180194

Singh, Janak,Bisacchi, Gregory S.,Ahmad, Saleem,Godfrey Jr., Jollie D.,Kissick, Thomas P.,Mitt, Toomas,Kocy, Octavian,Vu, Truc,Papaioannou, Chris G.,Wong, Michael K.,Heikes, James E.,Zahler, Robert,Mueller, Richard H.

, p. 393 - 399 (2013/09/08)

A practical synthesis of the antiviral agent lobucavir, [1R-(1α,2β,3α)]-2-amino-9-[2,3-bis(hydroxymethyl)cyclobutyl]- 6H-purin-6-one (BMS-180194), is described. The key chiral intermediate, [1S-(1α,2β,3α)]-3-hydroxy-1,2-cyclobutanedimethanol, dibenzoate e

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