138922-13-1

Basic information

• Product Name: tert-Butyl-[(2E,4E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenyloxy]-diphenyl-silane
• Synonyms: tert-Butyl-[(2E,4E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenyloxy]-diphenyl-silane
• CAS NO: 138922-13-1
• Molecular Weight: 524.862
• Mol File: 138922-13-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-Butyl-[(2E,4E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenyloxy]-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-[(2E,4E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenyloxy]-diphenyl-silane(138922-13-1)
• EPA Substance Registry System: tert-Butyl-[(2E,4E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenyloxy]-diphenyl-silane(138922-13-1)

Safety Data

• Hazardous Substances Data: 138922-13-1(Hazardous Substances Data)

Upstream product

• 6153-06-6 (E)-3-methylpent-2-en-4-yn-1-ol 
• 138846-07-8 tert-Butyl-((2E,4E)-5-iodo-3-methyl-penta-2,4-dienyloxy)-diphenyl-silane 
• 138846-06-7 2-[(1’E,3’E)-3’-methyl-4’-iodobuta-1’,3’-dien-1’yl]-1,3,3-trimethylcyclohex-1-ene 

Downstream Products

• 68-26-8 RETINOL 

Relevant articles and documents

Highly selective synthesis of vitamin A and its derivatives. Critical comparison of some known palladium-catalyzed alkenyl-alkenyl coupling reactions

Vitamin A has been synthesized cleanly and selectively with essentially complete control of stereo- and regiochemistry in four linear and six overall steps from β-ionone and (E)-3-methyl-2-penten-4-yn-1-ol via Pd-catalyzed cross coupling of an alkenylzinc with an alkenyl iodide; the use of other metals, such as Al, Zr, Mg, B, Cu, and Sn, being inferior to that of Zn.