13901-82-1Relevant articles and documents
Catalytic redox-neutral C-H functionalisation with TEMPO in water to access aminomethyl-substituted pyrroles
Cariello Silva, Guilherme,de Souza, Gabriela F. P.,Salles, Airton G.
supporting information, p. 3495 - 3500 (2022/05/02)
A redox-neutral C-H functionalisation in water employing catalytic TEMPO to synthesize aminomethyl-substituted pyrroles is reported. Starting from cheap and commercial chemical feedstocks (ketoesters and anilines), our approach delivered targeted products in good yields and represents an endeavour to address redox economy in radical transformations.
THE USE OF N-ETHYL-N'-DIMETHYLAMINOPROPYLCARBODIIMIDE OR SILICON TETRACHLORIDE IN PYRROLE SYNTHESES.
Anderson, Wayne K.,Heider, Arvela R.
, p. 357 - 364 (2007/10/02)
Two methods are used for mesoionic oxazolone formation in the synthesis of pyrroles in 1,3-dipolar cycloaddition reactions.N-ethyl-N'-dimethylaminopropylcarbodiimide or silicon tetrachloride are used to activate the N-acylamino acid.