13910-15-1

Basic information

• Product Name: (heptylsulfanyl)benzene
• Synonyms: (Heptylsulfanyl)benzene; benzene, (heptylthio)-; Heptyl phenyl sulfide
• CAS NO: 13910-15-1
• Molecular Formula: C₁₃H₂₀S
• Molecular Weight: 208.3629
• Mol File: 13910-15-1.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 295.464°C at 760 mmHg
• Flash Point: 128.495°C
• Density: 0.951g/cm³
• Vapor Pressure: 0.003mmHg at 25°C
• Refractive Index: 1.525
• CAS DataBase Reference: (heptylsulfanyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (heptylsulfanyl)benzene(13910-15-1)
• EPA Substance Registry System: (heptylsulfanyl)benzene(13910-15-1)

Safety Data

• Hazardous Substances Data: 13910-15-1(Hazardous Substances Data)

Upstream product

• 4282-40-0 1-Iodoheptane 
• 108-98-5 thiophenol 
• 591-50-4 iodobenzene 
• 1639-09-4 heptanethiol 
• 108-90-7 chlorobenzene 
• 51048-30-7 (cyclohexylthio)trimethylsilane 
• 111-71-7 heptanal 
• 629-04-9 1-Bromoheptane 
• 36219-92-8 1-heptenyl phenyl sulfide 
• 100-68-5 methyl-phenyl-thioether 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 930-69-8 sodium thiophenolate 
• 3238-98-0 3-phenylthio-1-bromopropane 
• 693-04-9 butyl magnesium bromide 

Downstream Products

• 96369-17-4 2-[3-(4-heptylsulfanyl-phenyl)-3-oxo-propyl]-1,1-dioxo-1,2-dihydro-1λ⁶-benzo[d]isothiazol-3-one 
• 661-11-0 1-fluoroheptane 
• 189638-40-2 heptyl phenyl sulfoxide 
• 93147-13-8 3-chloro-1-(4-heptylsulfanyl-phenyl)-propan-1-one 
• 111-14-8 oenanthic acid 

Relevant articles and documents

Cross-Coupling of Chloro(hetero)arenes with Thiolates Employing a Ni(0)-Precatalyst

A general and efficient Ni-catalyzed coupling of challenging aryl chlorides and in situ generated aliphatic and aromatic thiolates is described. The employed on-cycle, air-stable defined Ni precatalysts allow for transformation of a broad scope of substrates. A variety of functional groups and heterocyclic motifs as well as structurally varied thiols are tolerated at unprecedented moderate catalyst loadings and reaction temperatures. Depending on reaction conditions, aryl thiols can selectively undergo C-S or C-C couplings.

Efficient recyclable CuI-nanoparticle-catalyzed S-arylation of thiols with aryl halides on water under mild conditions

CuI nanoparticles efficiently catalyzed the C-S cross coupling of aryl and alkyl thiols with aryl halides in the absence of ligands on water under mild conditions. A wide range of diaryl sulfides and aryl alkyl sulfides are synthesized in good to excellent yields utilizing this protocol. This procedure is particularly noteworthy given its mild conditions, avoiding the undesired formation of disulfides through oxidation of thiols. The recovery and successful reutilization of the catalyst is described. Furthermore, the directed synthesis of bisarylated product is presented. The Royal Society of Chemistry 2012.

A concise route to D-erythro-sphingosine from N-Boc-L-serine derivatives via sulfoxide or sulfone intermediates

Sulfoxide and sulfone intermediates 7 and 15, respectively, were employed to synthesize synthons 3 and 4, which are readily converted to the naturally occurring (2S,3R,4(E))-sphingosine 1 and (2S,3R)-sphinganine 2.