139164-66-2

Upstream product

• 134276-93-0 Acetic acid (R)-5-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-8-methoxy-1,3-dimethyl-3,4-dihydro-isoquinolin-6-yl ester 
• 134276-93-0 O-acetylancistrocladinine 
• 134276-93-0 Acetic acid (S)-5-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-8-methoxy-1,3-dimethyl-3,4-dihydro-isoquinolin-6-yl ester 
• 134276-90-7 (-)-(S,1R)-N-<2-<3-benzyloxy-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-5-methoxyphenyl>-1-methylethyl>acetamide 
• 134276-92-9 Acetic acid 3-((R)-2-acetylamino-propyl)-2-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-5-methoxy-phenyl ester 
• 134276-89-4 (R)-2-[3-Benzyloxy-2-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-5-methoxy-phenyl]-1-methyl-ethylamine 
• 134276-91-8 (-)-(S,1R)-N-<2-<3-hydroxy-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-5-methoxyphenyl>-1-methylethyl>acetamide 
• 134276-97-4 (+)-(R,4S,5S)-4,5-dihydro-2-<1-<6-benzyloxy-4-methoxy-2-(5,5-dimethyl-1,3-dioxan-2-yl)phenyl>-4,5-dimethoxy-2-naphthyl>-4-methoxymethyl-5-phenyloxazole 
• 139077-46-6 1-[2-Benzyloxy-6-(5,5-dimethyl-[1,3]dioxan-2-yl)-4-methoxy-phenyl]-4,5-dimethoxy-naphthalene-2-carboxylic acid methyl ester 
• 139077-47-7 (-)-(R)-2-<3-benzyloxy-2-(2-hydroxymethyl-4,5-dimethoxy-1-naphthyl)-5-methoxyphenyl>-5,5-dimethyl-1,3-dioxane 
• 139077-40-0 1-(2-Benzyloxy-6-[1,3]dioxan-2-yl-4-methoxy-phenyl)-4,5-dimethoxy-naphthalene-2-carboxylic acid methyl ester 
• 139077-41-1 (-)-(R)-2-<3-benzyloxy-2-(2-hydroxymethyl-4,5-dimethoxy-1-naphthyl)-5-methoxyphenyl>-1,3-dioxane 
• 139077-42-2 (E)-(-)-(S)-1-<3-benzyloxy-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-5-methoxyphenyl>-2-nitropropene 
• 134276-88-3 (+)-(S)-3-benzyloxy-2-(4,5-dimethoxy-2-methyl-2-naphthyl)-5-methoxybenzaldehyde 

Downstream Products

• 32221-59-3 isoancistrocladine 

Relevant academic research and scientific papers

Synthetic Approaches to the Alkaloids of the Ancistrocladaceae: Control of the Diastereoisomer Excess in the Synthesis of Axially Chiral Biaryls: a Synthesis of (-)-Ancistrocladinine

An attempt is made to delineate the factors which comtrol the diastereoisomeric excess in the reactions of 2,6-disubstituted phenyl Grignard reagents with the naphthyloxazoline 2; advantage is taken of the results in a synthesis of the Ancistrocladus alka

Synthetic Approaches to the Alkaloids of the Ancistrocladaceae. Part 3. The Total Synthesis of (-)-Ancistrocladinine: Control of the Diastereoisomer Excess in the Synthesis of Axially Chiral Biaryls.

The total synthesis of the naphthylisoquinoline alkaloid (-)-ancistrocladinine is described.The key step was the construction of the disymmetric bi