32221-59-3

Basic information

• Product Name: ancistrocladine
• Synonyms: ancistrocladine;(1S)-1,2,3,4-Tetrahydro-6-hydroxy-8-methoxy-5-(4,5-dimethoxy-2-methyl-1-naphtyl)-1α,3β-dimethylisoquinoline;5-(4,5-Dimethoxy-2-methyl-1-naphtyl)-1,2,3,4-tetrahydro-8-methoxy-1α,3β-dimethylisoquinolin-6-ol;6-O-Methyl-4'-O-demethylhamatine;5-(4,5-Dimethoxy-2-methyl-1-naphthalenyl)-1,2,3,4-tetrahydro-8-methoxy-1,3-dimethyl-6-isoquinolinol;6-Isoquinolinol, 5-(4,5-dimethoxy-2-methyl-1-naphthalenyl)-1,2,3,4-tetrahydro-8-methoxy-1,3-dimethyl-, stereoisomer;Ancistrocladin
• CAS NO: 32221-59-3
• Molecular Formula: C25H29NO4
• Molecular Weight: 407.5
• Mol File: 32221-59-3.mol

Chemical Properties

• Boiling Point: 565.3°Cat760mmHg
• Flash Point: 295.7°C
• Appearance: /
• Density: 1.137g/cm³
• Vapor Pressure: 2.2E-13mmHg at 25°C
• Refractive Index: 1.586
• CAS DataBase Reference: ancistrocladine(CAS DataBase Reference)
• NIST Chemistry Reference: ancistrocladine(32221-59-3)
• EPA Substance Registry System: ancistrocladine(32221-59-3)

Safety Data

• Hazardous Substances Data: 32221-59-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C25H29NO4/c1-13-10-20(29-5)25-16(8-7-9-19(25)28-4)22(13)24-17-11-14(2)26-15(3)23(17)21(30-6)12-18(24)27/h7-10,12,14-15,26-27H,11H2,1-6H3/t14-,15-/m0/s1

Upstream product

• 104292-16-2 (1S,3S)-2-Benzyl-5-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-8-methoxy-1,3-dimethyl-1,2,3,4-tetrahydro-isoquinolin-6-ol 
• 18917-77-6 (3,5-dimethoxyphenyl)acetone 
• 104292-11-7 1-Bromo-4,5-dimethoxy-naphthalene-2-carbonyl chloride 
• 104292-12-8 (1S,3S)-2-Benzyl-8-methoxy-1,3-dimethyl-1,2,3,4-tetrahydro-isoquinolin-6-ol 
• 92264-14-7 1-bromo-2-(bromomethyl)-4,5-dimethoxynaphthalene 
• 104292-14-0 (12S,14S)-13-Benzyl-1,6,7-trimethoxy-12,14-dimethyl-11,12,13,14-tetrahydro-3-oxa-13-aza-dibenzo[c,g]phenanthren-4-one 
• 104292-15-1 (1S,3S)-2-Benzyl-5-(2-hydroxymethyl-4,5-dimethoxy-naphthalen-1-yl)-8-methoxy-1,3-dimethyl-1,2,3,4-tetrahydro-isoquinolin-6-ol 
• 104292-13-9 1-Bromo-4,5-dimethoxy-naphthalene-2-carboxylic acid (1S,3S)-2-benzyl-8-methoxy-1,3-dimethyl-1,2,3,4-tetrahydro-isoquinolin-6-yl ester 
• 104371-22-4 (2S)-1-(3',5'-dimethoxyphenyl)-2-aminopropane 
• 104292-10-6 (1S,3S)-6,8-Dimethoxy-1,3-dimethyl-1,2,3,4-tetrahydro-isoquinoline 
• 104292-08-2 (S)-6,8-dimethoxy-1,3-dimethyl-3,4-dihydroisoquinoline 
• 36209-87-7 (-)-ancistrocladinine 

Relevant articles and documents

(+)-ANCISTROCLINE, A NAPHTHYLISOQUINOLINE ALKALOID FROM ANCISTROCLADUS TECTORIUS

The completion of the structural elucidation of (+)-ancistrocline, a naphthylisoquinoline alkaloid from Ancistrocladus tectorius, by partial synthesis from the known alkaloid, ancistrocladinine, is described.By this transformation, the constitution of (+)-ancistrocline is confirmed, and its stereostructure established as 1R,3S,5S.Key Word Index: Ancistrocladus tectorius; Ancistrocladaceae; (+)-ancistrocline; structural elucidation; partial synthesis; ancistrocladinine; naphthylisoquinoline alkaloids.