1391738-90-1

Basic information

• Product Name: (2,4-bis(2,4,6-triphenylphenylimido)-3-pentyl)Li(OEt₂)
• Synonyms: (2,4-bis(2,4,6-triphenylphenylimido)-3-pentyl)Li(OEt₂)
• CAS NO: 1391738-90-1
• Molecular Weight: 786.986
• Mol File: 1391738-90-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2,4-bis(2,4,6-triphenylphenylimido)-3-pentyl)Li(OEt₂)(CAS DataBase Reference)
• NIST Chemistry Reference: (2,4-bis(2,4,6-triphenylphenylimido)-3-pentyl)Li(OEt₂)(1391738-90-1)
• EPA Substance Registry System: (2,4-bis(2,4,6-triphenylphenylimido)-3-pentyl)Li(OEt₂)(1391738-90-1)

Safety Data

• Hazardous Substances Data: 1391738-90-1(Hazardous Substances Data)

Upstream product

• 6864-20-6 2,4,6-triphenylaniline 
• 10368-47-5 2-nitro-1,3,5-triphenyl-benzene 
• 60-29-7 diethyl ether 

Relevant articles and documents

Ligand effects on hydrogen atom transfer from hydrocarbons to three-coordinate iron imides

A new β-diketiminate ligand with 2,4,6-tri(phenyl)phenyl N-substituents provides protective bulk around the metal without exposing any weak C-H bonds. This ligand improves the stability of reactive iron(III) imido complexes with Fe=NAd and Fe=NMes functional groups (Ad = 1-adamantyl; Mes = mesityl). The new ligand gives iron(III) imido complexes that are significantly more reactive toward 1,4-cyclohexadiene than the previously reported 2,6-diisopropylphenyl diketiminate variants. Analysis of X-ray crystal structures implicates Fe=N-C bending, a longer Fe=N bond, and greater access to the metal as potential reasons for the increase in C-H bond activation rates.