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10368-47-5

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10368-47-5 Usage

General Description

2,4,6-triphenylnitrobenzene is a chemical compound with the molecular formula C18H13NO2. It is a yellow crystalline solid that is insoluble in water and is primarily used in research as a precursor in the synthesis of various organic compounds. It is also used as a building block for the production of pharmaceuticals, dyes, and agrochemicals. 2,4,6-triphenylnitrobenzene is known to be harmful if swallowed, inhaled, or come into contact with the skin or eyes, and should be handled with proper safety precautions. Additionally, it is considered to be a potential environmental pollutant and should be disposed of according to regulations.

Check Digit Verification of cas no

The CAS Registry Mumber 10368-47-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,3,6 and 8 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 10368-47:
(7*1)+(6*0)+(5*3)+(4*6)+(3*8)+(2*4)+(1*7)=85
85 % 10 = 5
So 10368-47-5 is a valid CAS Registry Number.
InChI:InChI=1/C24H17NO2/c26-25(27)24-22(19-12-6-2-7-13-19)16-21(18-10-4-1-5-11-18)17-23(24)20-14-8-3-9-15-20/h1-17H

10368-47-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,4,6-Triphenylnitrobenzene

1.2 Other means of identification

Product number -
Other names 2-nitro-1,3,5-triphenylbenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10368-47-5 SDS

10368-47-5Related news

On the electrochemistry of 2,4,6-TRIPHENYLNITROBENZENE (cas 10368-47-5) and related compounds07/29/2019

Cyclic voltammetry at a glassy carbon electrode of 2,4,6-triphenylnitrobenzene (1) in DMF shows two reversible one-electron reductions. Preparative reduction of 1 yields 2,4,6-triphenylaniline under both acidic and alkaline conditions and in DMF in the presence of acetic anhydride. On reduction ...detailed

10368-47-5Relevant articles and documents

Yoshida et al.

, p. 6083,6087 (1971)

Cobalt schiff base complex-catalyzed oxidation of anilines with tert-butyl hydroperoxide

Foerster, Stefan,Rieker, Anton,Maruyama, Kazushige,Murata, Kunihiko,Nishinaga, Akira

, p. 3320 - 3326 (2007/10/03)

Cobalt Schiff base complexes [Co(SB)] catalyze the oxidation of anilines (1) with tert-butyl hydroperoxide to give nitrobenzenes 2 and 4-(tert-butylperoxy)-2,5-cyclohexadien-1-imine derivatives 3 in yield distributions depending on the substitution mode of the substrate. 4-Alkyl- and 4-aryl-2,6-di-tert-butylanilines gave mixtures of 2 and 3, where the higher the bulkiness of the 4-substituent, the higher the yield of 2. With 2,4,6-trimethylaniline, the ratio of oxidations of the nitrogen and C-4 atoms was almost the same; but a hydrolyzed product 5 of the imine was obtained. 2,4,6-Triphenylaniline gave only 2. Nitrobenzene derivatives were also obtained from 2,6-dialkylanilines and 4-substituted anilines. The catalytic activity of Co(SB) depended on the nature of the SB ligand: the formal potential E° and steric factors seem to affect the reaction rate. Kinetic studies showed that the key step may involve hydrogen abstraction from the aniline, presumably by t-BuO? generated from homolytic decomposition of initially formed CoIII(SB)(OO-t-Bu). A precursor of 2 was found to be the nitrosobenzene derivative.

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