139259-62-4

Upstream product

• 4837-31-4 4-Phenylsulfanyl-morpholine 
• 78-79-5 isoprene 
• 54815-45-1 ethyl benzenesulfenate 

Downstream Products

• 139259-46-4 (E)-(1S,10S)-1,5,8,8-Tetramethyl-4-phenylsulfanyl-bicyclo[8.1.0]undec-5-en-2-ol 
• 139259-45-3 (1S,2S)-1-Methyl-2-((E)-2,2,5-trimethyl-6-phenylsulfanyl-hex-4-enyl)-cyclopropanecarbaldehyde 
• 139290-32-7 2-[(1S,2S)-1-Methyl-2-((E)-2,2,5-trimethyl-6-phenylsulfanyl-hex-4-enyl)-cyclopropyl]-oxirane 
• 139259-44-2 [(1S,2S)-1-Methyl-2-((E)-2,2,5-trimethyl-6-phenylsulfanyl-hex-4-enyl)-cyclopropyl]-methanol 
• 71493-03-3 (+)-Bicyclohumulenone 

Relevant academic research and scientific papers

A new method for the activation of ethyl benzenesulfenate in electrophilic addition reactions

Reactions of unsaturated compounds with the PhSOEt-SOHal2 and PhSOEt-Me3SiHal systems (Hal = Cl or Br) were proposed as a new route to haloalkyl phenyl sulfides. With acyclic and mono- and bicyclic alkenes and dienes as examples, the

Halosulfenylation of Conjugated Dienes with Arylsulfenamides in the Presence of Phosphorus Oxyhalides

Electrophilic sulfenylation of cyclic and open-chain conjugated dienes effected by a system arylsulfenamide-phosphorus oxyhalide was investigated. The initially formed adducts of 1,2-halosulfenylation in the course of the reaction and also at storage and chromatograqphic purification on silica gel undergo quantitative isomerization into a mixture of stereoisomeric products of 1,4-addition. The effect of halogen nature and the character of substituents in the benzene ring of arenesulfenamide on the addition rate of sulfenamides activated by phosphorus oxyhalides to open-chain and cyclic conjugated dienes and isomerization rate of the arising 1,2-adducts was examined.