1392823-75-4

Upstream product

• 1392823-73-2 (4R,5R,6S,E)-7-(tert-butyldiphenylsilyloxy)-5-hydroxy-4,6-dimethyl-1-phenylhept-2-en-1-one 
• 1392823-74-3 (1R,4R,5R,6S,E)-7-(tert-butyldiphenylsilyloxy)-4,6-dimethyl-1-phenylhept-2-ene-1,5-diol 
• 108-24-7 acetic anhydride 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 92817-88-4 (2S)-3-{[tert-butyl(diphenyl)silyl]oxy}-2-methylpropanal 
• 95514-04-8 (R)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 
• 91751-27-8 (3R,4R,5S)-6-(tert-butyldiphenylsiloxy)-4-hydroxy-3,5-dimethylhexan-1-ene 
• 95514-03-7 (S)-3-(tert-butyl-diphenyl-silanyloxy)-2-methyl-propionic acid methyl ester 
• 100-52-7 benzaldehyde 

Downstream Products

• 307492-68-8 (1R,4R,5R,6S,E)-7-(tert-butyldiphenylsilyloxy)-4,6-dimethyl-1-phenylhept-1-ene-3,5-diyl diacetate 

Relevant academic research and scientific papers

Step-economic synthesis of (+)-crocacin C: A concise crotylboronation/[3,3] -sigmatropic rearrangement approach

The step-economic total synthesis of (+)-crocacin C has been achieved in 20% yield from commercially available starting materials. This approach requires the isolation of only 8 intermediates and can provide a reliable supply of (+)-crocacin C for the development of new antifungal and crop protection agents.