139489-26-2Relevant academic research and scientific papers
THIOCYANOARYLATION OF VINYL AND VINYLIDENE CHLORIDES
Grishchuk, B. D.,Gorbovoi, P. M.,Kudrik, E. Ya.,Ganushchak, N. I
, p. 2396 - 2401 (2007/10/02)
A method was developed for the preparation of chlorine-containing aliphatic-aromatic thicyanates (1-chloro- and 1,1-dichloro-1-thiocyanato-2-arylethanes) by reactions of arenediazonium tetrafluoroborates with vinyl chloride and with vinylidene chloride in presence of potassium (sodium or ammonium) thocyanate.A necessary condition for success in the reaction is the presence of a catalyst: Cu(II) or Fe(II) thicyanate.
