1396022-02-8Relevant articles and documents
Asymmetric Synthesis of amines through rhodium-catalyzed C-H amination with sulfonimidoylnitrenes
Darses, Benjamin,Jarvis, Amandag.,Mafroud, Abdel-Kader,Estenne-Bouhtou, Genevieve,Dargazanli, Gihad,Dauban, Philippe
, p. 2079 - 2087 (2013/08/23)
An efficient asymmetric C-H amination of benzylic and allylic substrates, as well as of adamantane derivatives, through catalytic C-H insertion of a chiral nitrene is reported. The reaction involves a chiral rhodium(II) complex, an iodine(III) oxidant, an