139639-76-2

Upstream product

• 56607-40-0 methyl D-arabinofuranoside 
• 189324-80-9 (2R,3R,4S,5S)-2-[Bis-(4-methoxy-phenyl)-phenyl-methoxymethyl]-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-tetrahydro-furan 
• 189324-79-6 Methyl 2,3-di-O-(tert-butyldimethylsilyl)-5-O-pivaloyl-α-D-arabinofuranoside 
• 139639-70-6 methyl 2,3-bis-O-tert-butyldimethylsilyl-α-D-arabino-pentodialdofuranoside-(1,4) 
• 139639-69-3 Methyl 2,3-di-O-(tert-butyldimethylsilyl)-α-D-arabinofuranoside 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 139639-72-8 Methyl 2,3-di-O-(tert-butyldimethylsilyl)-6-deoxy-α-D-altrofuranoside 
• 98-59-9 p-toluenesulfonyl chloride 
• 7473-42-9 methyl tri-O-benzoyl-α-D-arabinofuranoside 

Relevant academic research and scientific papers

Syntheses of L-Fucopyranose and Its Homologs with Ring Heteroatoms Other than Oxygen. Sterocontrolled Conversion of the Common D-Arabinofuranoside Intermediate

L-Fucopyranose and a couple of L-fucosidase inhibitors, 5-deoxy-5-thio-L-fucopyranose and 1,5-dideoxy-1,5-imino-L-fucitol, were prepared from a common pentose intermediate with α-D-arabino configuration.Stereoselectivities on carbon chain elongation of th

Simple syntheses of L-fucopyranose and fucosidase inhibitors utilizing the highly stereoselective methylation of an arabinofuranoside 5-urose derivative

The simple syntheses of L-fucopyranose 1 and its three analogues 2-4 are described. A key reaction is a stereocontrolled elongation by one carbon unit at the side chain of an α-D-arabino-pentodialdo-1,4-furanoside 9 with MeMgI-ZnCl2 or Me3Al. Diastereofacial selectivities of more than 92% were achieved.