189324-80-9Relevant academic research and scientific papers
Simple syntheses of L-fucopyranose and fucosidase inhibitors utilizing the highly stereoselective methylation of an arabinofuranoside 5-urose derivative
Takahashi, Shunya,Kuzuhara, Hiroyoshi
, p. 607 - 612 (2007/10/03)
The simple syntheses of L-fucopyranose 1 and its three analogues 2-4 are described. A key reaction is a stereocontrolled elongation by one carbon unit at the side chain of an α-D-arabino-pentodialdo-1,4-furanoside 9 with MeMgI-ZnCl2 or Me3Al. Diastereofacial selectivities of more than 92% were achieved.
