139686-86-5Relevant academic research and scientific papers
Regioselective functionalization of unprotected myo-inositol by electrophilic substitution
Watanabe, Yutaka,Uemura, Tsuyoshi,Yamauchi, Satoe,Tomita, Kousei,Saeki, Takafumi,Ishida, Ryousuke,Hayashi, Minoru
, p. 4657 - 4664 (2013/06/26)
Unprotected myo-inositol was treated with various electrophiles, such as aroyl chlorides, tosyl chloride and tert-butyldiphenylsilyl chloride in a solution of LiCl/DMA or DMSO to afford regioselectively 1,3-di-O-substituted or racemic 1-O-substituted deri
Synthesis of D-erythro-sphingomyelin and of D-erythro-ceramide-1-phosphoinositol
Kratzer, Bernd,Mayer, Thomas G.,Schmidt, Richard R.
, p. 6881 - 6884 (2007/10/02)
3-O-Silyl-protected azidosphingosine 3, readily available from D-erythro-azidosphingosine, is transformed into ceramidyl phosphite derivative 5 which is a versatile building block for the synthesis of ceramide-1-O-phosphate and derivatives. This is exhibited for the synthesis of the title compounds 1 and 2.
The regioselective synthesis of enantiomerically pure myo-inositol derivatives. Efficient synthesis of myo-inositol 1,4,5-trisphosphate
Aguilo, Agustin,Martin-Lomas, Manuel,Penades, Soledad
, p. 401 - 404 (2007/10/02)
Regioselective 1-O-acylation of myo-inositol and simultaneous optical resolution has been achieved by perborylation, transmetallation using di-n-butyltin-bis-acetylacetonate and then acylation with (-)-menthyl chloroformate. Diastereomerically pure 1-O-(-
