1397290-31-1Relevant articles and documents
Palladium-catalyzed C(sp2) - H cyanation using tertiary amine derived isocyanide as a cyano source
Peng, Jiangling,Zhao, Jiaji,Hu, Ziwei,Liang, Dongdong,Huang, Jinbo,Zhu, Qiang
supporting information, p. 4966 - 4969,4 (2012/12/12)
An unprecedented palladium-catalyzed cyanation of aromatic C-H bonds by using tertiary amine derived isocyanide as a novel cyano source was developed. Cu(TFA)2 was used as a requisite stoichiometric oxidant. Mechanistic studies suggest that a tertiary carbon cation-based intermediate is involved following the C-N bond breakage.