139884-17-6

Basic information

• Product Name: Benzene, 1-[(methoxymethoxy)methyl]-4-nitro-
• CAS NO: 139884-17-6
• Molecular Formula: C9H11NO4
• Molecular Weight: 197.191
• Mol File: 139884-17-6.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(methoxymethoxy)methyl]-4-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(methoxymethoxy)methyl]-4-nitro-(139884-17-6)
• EPA Substance Registry System: Benzene, 1-[(methoxymethoxy)methyl]-4-nitro-(139884-17-6)

Safety Data

• Hazardous Substances Data: 139884-17-6(Hazardous Substances Data)

Upstream product

• 619-73-8 4-nitrobenzyl chloride 
• 109-87-5 Dimethoxymethane 
• 107-30-2 chloromethyl methyl ether 
• 4382-76-7 methoxymethyl acetate 

Downstream Products

• 619-73-8 4-nitrobenzyl chloride 
• 14856-73-6 4-nitrobenzyl trimethylsilyl ether 
• 619-90-9 4-nitrobenzyl acetate 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 3145-86-6 4-nitrobenzyl iodide 
• 555-21-5 4-Nitrophenylacetonitrile 

Relevant articles and documents

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A simple, green and chemoselective method for methoxymethylation and ethoxymethylation of primary and secondary alcohols using a Lewis acidic room temperature ionic liquid, [C4mim][InCl4], as catalyst and reaction medium under ambient temperature, microwave and ultrasonic irradiations is reported. In this catalytic system, the corresponding MOM-and EOM-ethers are obtained in excellent yields and in short reaction times. Furthermore, this catalytic system was used for mild and efficient transformations of these protected alcohols to their corresponding acetates and trimethylsilyl ethers under thermal conditions and microwave and ultrasonic irradiations.

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