1399175-22-4

Upstream product

• 123-75-1 pyrrolidine 
• 108-42-9 3-chloro-aniline 

Downstream Products

• 1399175-50-8 (E)-benzyl-3-(4-chloro-2-((E)-pyrrolidin-1-yldiazenyl)phenyl)acrylate 
• 1399175-63-3 (2E,2'E)-benzyl 3,3'-(4-chloro-2-((E)-pyrrolidin-1-yldiazenyl)-1,3-phenylene)diacrylate 
• 66785-53-3 6-chloro-2,3-diphenyl-1H-indole 

Relevant academic research and scientific papers

General and efficient synthesis of indoles through triazene-directed c-h annulation

Unprotected indoles are prepared with the title method, which has a wide scope for alkynes. Excellent regioselectivity was accomplished for aryl-alkyl and alkyl-alkyl disubstituted acetylenes. This reaction features an unusual 1,2 rhodium migration and ring-contraction-triggered N-N bond cleavage. It allows rapid conversion of the reaction products into several functional molecules. Copyright

Rhodium(III)-catalyzed C-H activation of arenes using a versatile and removable triazene directing Group

Diverse opportunities: A Rhodium(III)-catalyzed ortho-selective olefination of arenes using a novel triazene as a directing group is reported. This method exhibits substantial post-functionalization synthetic versatility, overcoming a vital limitation in Ca spa 2-H activation/functionalization products: restricted structural diversity. Copyright