139965-06-3Relevant academic research and scientific papers
Synthesis of Enantiomerically Pure Fluoro- and gem-Chlorofluorocyclohexane Derivatives
Arnone, Alberto,Bravo, Pierfrancesco,Frigerio, Massimo,Viani, Fiorenza,Cavicchio, Giancarlo,Crucianelli, Marcello
, p. 6448 - 6455 (2007/10/02)
gem-Chlorofluorocyclohexanols 10 are prepared in good yields by radical-promoted cyclization from the corresponding ω-dichlorofluoroheptenols 4.Fluorocyclohexanols 11 are obtained either from 10 or in a single step from open-chain alcohols 4.The stereoche
Synthesis of Optically Pure Fluoro- and gem-Chlorofluoro-cyclohexane Derivatives by Intramolecular Trapping of Dihaloalkyl Radicals.
Arnone, Alberto,Bravo, Pierfrancesco,Cavicchio, Giancarlo,Frigerio, Massimo,Viani, Fiorenza
, p. 9 - 12 (2007/10/02)
gem-Chlorofluorocyclohexanols 8 bearing a methyl and a p-tolylsulphinyl substituent have been obtained in a optically pure form by radical cyclization of corresponding halo-alkenes 4.Reductive dechlorination of both (6R)- and (6S)-8 gave fluoroderivative
