14003-15-7Relevant articles and documents
Cobalt-Catalyzed Oxygenation/Dearomatization of Furans
Oswald, Jonathan P.,Woerpel
, p. 9067 - 9075 (2018/05/29)
The dearomatization of aromatic compounds using cobalt(II) acetylacetonate with triplet oxygen and triethylsilane converts furans, benzofurans, pyrroles, and thiophenes to a variety of products, including lactones, silyl peroxides, and ketones.
Hydrogenation of ketones with a manganese PN3P pincer pre-catalyst
Bruneau-Voisine, Antoine,Wang, Ding,Roisnel, Thierry,Darcel, Christophe,Sortais, Jean-Baptiste
, p. 1 - 4 (2017/01/10)
A catalytic hydrogenation of carbonyl derivatives with a manganese pre-catalyst has been developed. The key feature is the use of an air stable cationic manganese pre-catalyst bearing a tridendate ligand with a 2,6-(diaminopyridinyl)diphosphine scaffold. Under 50?bar of H2, at 130?°C, various ketones were reduced to the corresponding alcohols with moderate to good yield.
Ansa-Ruthenium(II) Complexes of R2NSO2DPEN-(CH2)n(η6-Aryl) Conjugate Ligands for Asymmetric Transfer Hydrogenation of Aryl Ketones
Ki?ic, Andrea,Stephan, Michel,Mohar, Barbara
supporting information, p. 2540 - 2546 (2015/08/18)
New 3rd generation designer ansa-ruthenium(II) complexes featuring N,C-alkylene-tethered N,N-dialkylsulfamoyl-DPEN/η6-arene ligands, exhibited good catalytic performance in the asymmetric transfer hydrogenation (ATH) of various classes of (het)aryl ketones in formic acid/triethylamine mixture. In particular, benzo-fused cyclic ketones furnished 98 to >99.9% ee using a low catalyst loading.
