1400695-38-6

Basic information

• Product Name: tert-butyl ((2R,3R)-1,2-dihydroxy-6-phenylhexan-3-yl)carbamate
• CAS NO: 1400695-38-6
• Molecular Weight: 309.406
• Mol File: 1400695-38-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl ((2R,3R)-1,2-dihydroxy-6-phenylhexan-3-yl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl ((2R,3R)-1,2-dihydroxy-6-phenylhexan-3-yl)carbamate(1400695-38-6)
• EPA Substance Registry System: tert-butyl ((2R,3R)-1,2-dihydroxy-6-phenylhexan-3-yl)carbamate(1400695-38-6)

Safety Data

• Hazardous Substances Data: 1400695-38-6(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 1400695-56-8 C₁₂H₁₇N₃O₂ 

Downstream Products

• 1400695-48-8 methyl (2R,3R)-3-((tert-butoxycarbonyl)amino)-2-hydroxy-6-phenylhexanoate 
• 1400695-41-1 (R)-methyl 2-((tert-butoxycarbonyl)amino)-5-phenylpentanoate 
• 156130-68-6 2-(tert-butoxycarbonylamino)-5-phenyl-D-pentanoic acid 
• 98628-27-4 2-tert-butoxycarbonylamino-5-phenyl-pentanoic acid 

Relevant articles and documents

Organocatalytic one-pot oxidative cleavage of terminal diols to dehomologated carboxylic acids

The organocatalytic one-pot oxidative cleavage of terminal 1,2-diols to one-carbon-unit-shorter carboxylic acids is described. The combination of 1-Me-AZADO (cat.), NaOCl (cat.), and NaClO2 caused smooth one-pot oxidative cleavage under mild conditions. A broad range of substrates including carbohydrates and N-protected amino diols were converted without epimerization. Terminal triols and tetraols respectively underwent cleavage of their C-2 and C-3 moieties to afford their corresponding two- and three-carbon-unit-shorter carboxylic acids.