140149-26-4

Basic information

• Product Name: (η5-C5H5)Fe(CO)2Si(t-Bu)2H
• CAS NO: 140149-26-4
• Molecular Weight: 320.287
• Mol File: 140149-26-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η5-C5H5)Fe(CO)2Si(t-Bu)2H(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-C5H5)Fe(CO)2Si(t-Bu)2H(140149-26-4)
• EPA Substance Registry System: (η5-C5H5)Fe(CO)2Si(t-Bu)2H(140149-26-4)

Safety Data

• Hazardous Substances Data: 140149-26-4(Hazardous Substances Data)

Upstream product

• 56310-18-0 di-tert-butylchlorosilane 

Relevant articles and documents

SYNTHESE UND REAKTIVITAET VON SILICIUM-UEBERGANGSMETALLKOMPLEXEN. XV. EISEN-SILANE MIT SPERRIGEN ALKYL-LIGANDEN AM SILICIUM

The chlorosilanes RSiHCl2 react with Na to give the iron silanes Cp(CO)2FeSiHRCL (Ia-Ic) (R=Et (a), i-Pr (b), t-Bu (c)), which are chlorinated by CCl4 to Cp(CO)2FeSiRCl2 (IIa-IIc).AgBF4 transforms IIb and IIc into the iron fluorosilanes Cp(CO)2FeSiRF2 (IIIb, IIIc).The structure of the new silicon iron complexes is determined by means fo their IR and NMR spectra (1H, 13C, 19F, 29Si).A correlation between the values of ν(SiH) and J(SiH) of Ia-Ic and the Taft constants ? of R is established.