1402067-59-7Relevant articles and documents
α-Amino Acetal: A Synthetic Intermediate for the Construction of Aza-Polycycles
Liu, Duan-Yang,Zhu, Si-Mao,Li, Rui-Qi,Tian, Jie-Sheng,Loh, Teck-Peng
supporting information, p. 6357 - 6360 (2019/09/06)
One-step construction of aza-polycyclic skeletons was realized through double cyclization of the oxocarbenium and carbocation intermediates generated from α-amino acetals, which were designed and synthesized by employing our α-amination protocol of aldehy
α-amination of aldehydes catalyzed by in situ generated hypoiodite
Tian, Jie-Sheng,Ng, Kang Wai Jeffrey,Wong, Jiun-Ru,Loh, Teck-Peng
supporting information, p. 9105 - 9109 (2012/10/29)
The metal-free amination of different aldehydes is catalyzed by hypoiodite, which is generated by employing commercially available sodium percarbonate as the co-oxidant. This approach has several advantages: it is a metal-free oxidation that works under m