1402153-10-9Relevant academic research and scientific papers
α,n-didehydrotoluenes by photoactivation of (chlorobenzyl) trimethylsilanes: An alternative to enyne-allenes cyclization
Protti, Stefano,Ravelli, Davide,Mannucci, Barbara,Albini, Angelo,Fagnoni, Maurizio
, p. 8577 - 8580 (2012)
Doubly radical: A novel entry to ?,n-didehydrotoluene (DHT) diradicals is disclosed and proceeds through the photochemical activation of (chlorobenzyl)trimethylsilanes with chloride loss and elimination of the SiMe3+ group (see scheme). The products formed in solution are indicative of the intermediacy of the three isomers of the ?,n-DHT
