140238-92-2Relevant academic research and scientific papers
SYNTHESIS OF UNSATURATED TERTIARY AMINES AND α-ALLYL SUBSTITUTED KETONES FROM AZOMETHINES USING METAL COMPLEX CATALYSTS
Ibragimov, A. G.,Minsker, D. L.,Morozov, A. B.,Galkin, E. M.,Dzhemilev, U. M.,Tolstikov, G. A.
, p. 140 - 144 (2007/10/02)
A method has been developed for the regioselective synthesis of unsaturated tertiary amines via the reaction of magnesium amides, derived from Schiff bases, with allylic electrophiles in the presence of Pd and Cu complexes.The reaction of ketimines which
PALLADIUM-CATALYZED ALLYLATION OF KETONES AND ALDEHYDES WITH ALLYLIC CARBONATES VIA SILYL ENOL ETHERS UNDER NEUTRAL CONDITIONS
Tsuji, Jiro,Minami, Ichiro,Shimizu, Isao
, p. 1325 - 1326 (2007/10/02)
Silyl enol ethers are converted to 2-allyl ketones and aldehydes by the reaction with allylic carbonates in the presence of a palladium-phosphine catalyst.
