6407-35-8

Basic information

• Product Name: N-Cyclohexylidenemethanamine
• Synonyms: N-Cyclohexylidenemethanamine
• CAS NO: 6407-35-8
• Molecular Formula: C₇H₁₃N
• Molecular Weight: 111.18
• Mol File: 6407-35-8.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 149.9±9.0 °C(Predicted)
• Appearance: /
• Density: 0.92±0.1 g/cm3(Predicted)
• PKA: 7.71±0.20(Predicted)
• CAS DataBase Reference: N-Cyclohexylidenemethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Cyclohexylidenemethanamine(6407-35-8)
• EPA Substance Registry System: N-Cyclohexylidenemethanamine(6407-35-8)

Safety Data

• Hazardous Substances Data: 6407-35-8(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 74-89-5 methylamine 
• 58751-78-3 N-cyclohexylidenemethanamine N-oxide 
• 616-38-6 carbonic acid dimethyl ester 

Downstream Products

• 33542-26-6 N-1-cyclohexenyl-N-methylcarbamyl chloride 
• 16240-36-1 3',4'-Dichlor-2-oxo-thiocyclohexan-carbanilid 
• 82988-53-2 N-(1-cyclohexenyl)-N-methyl-α-(methylsulfinyl)acetamide 
• 1196-52-7 7-Methyl-cis-7-azabicyclo<4.3.0>nonan-8-one 
• 51265-33-9 1-methyl-4,5,6,7-tetrahydro-1H-indole 
• 62372-19-4 1,2-Dimethyl-4,5,6,7-tetrahydro-indol 
• 134339-65-4 (3R*,3aS*,7aS*)-octahydro-1-methyl-3-phenylindol-2-one 
• 134339-65-4 (3S*,3aS*,7aS*)-octahydro-1-methyl-3-phenylindol-2-one 
• 134339-75-6 (3R^*,3aR^*,7aS^*)-Octahydro-1-methyl-3-(phenylthio)indol-2-one 
• 134339-75-6 (3S*,3aR*,7aS*)-octahydro-1-methyl-3-(phenylthio)indol-2-one 
• 134339-61-0 N-(cyclohex-1-enyl)-N-methyl-2,2-bis(phenylthio)acetamide 
• 134339-77-8 N-(cyclohex-1-enyl)-N-methyl-2-(phenylthio)acetamide 
• 312326-18-4 N-(cyclohex-1-enyl)-N-methyl-2-iodopropionamide 

Relevant articles and documents

Asymmetric and Geometry-Selective α-Alkenylation of α-Amino Acids

Both E- and Z-N′-alkenyl urea derivatives of imidazolidinones may be formed selectively from enantiopure α-amino acids. Generation of their enolate derivatives in the presence of K+ and [18]crown-6 induces intramolecular migration of the alkeny

Intramolecular vinylation of secondary and tertiary organolithiums

Deprotonation of benzylic ureas, carbamates, and thiocarbamates bearing N′-alkenyl substituents generates carbanions which undergo intramolecular migration of the alkenyl group to the carbanionic center. Solvolysis of the urea products generates α-alkenylated amines. With an enantiomerically pure starting urea, migration proceeds stereospecifically, generating in enantiomerically enriched form products containing allylic quaternary stereogenic centers bearing N. Computational and in situ IR studies suggest that the reaction, formally a nucleophilic substitution at an sp2 carbon atom, proceeds by a concerted addition-elimination pathway.

Method for preparing aromatic secondary amino compound

Disclosed are (1) a method for preparing an aromatic secondary amino compound which comprises reacting an N-cyclohexylideneamino compound in the presence of a hydrogen moving catalyst and a hydrogen acceptor by the use of a sulfur-free polar solvent and/or a cocatalyst, and (2) a method for preparing an aromatic secondary amino compound which comprises reacting cyclohexanone or a nucleus-substituted cyclohexanone, an amine and a nitro compound corresponding to the amine in a sulfur-free polar solvent in the presence of a hydrogen moving catalyst, a cocatalyst being added or not added. In a further aspect, a method is provided for the preparation of aminodiphenylamine by reacting phenylenediamine and cyclohexanone in the presence of a hydrogen transfer catalyst in a sulfur-free polar solvent while using nitroaniline as a hydrogen acceptor.