1402454-70-9

Basic information

• Product Name: methyl (Z)-2-bromo-3-(2-nitrophenyl)propenoate
• Synonyms: methyl (Z)-2-bromo-3-(2-nitrophenyl)propenoate
• CAS NO: 1402454-70-9
• Molecular Weight: 286.082
• Mol File: 1402454-70-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl (Z)-2-bromo-3-(2-nitrophenyl)propenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-2-bromo-3-(2-nitrophenyl)propenoate(1402454-70-9)
• EPA Substance Registry System: methyl (Z)-2-bromo-3-(2-nitrophenyl)propenoate(1402454-70-9)

Safety Data

• Hazardous Substances Data: 1402454-70-9(Hazardous Substances Data)

Upstream product

• 552-89-6 2-nitro-benzaldehyde 
• 75-98-9 Trimethylacetic acid 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 1586740-56-8 (Z)-methyl 3-(2-aminophenyl)-2-bromoacrylate 
• 1586740-68-2 (Z)-methyl 3-(2-amino-5-bromophenyl)-2-bromoacrylate 
• 1586740-69-3 (Z)-methyl 3-(2-amino-5-iodophenyl)-2-bromoacrylate 
• 1586740-70-6 (Z)-methyl 3-(2-amino-3,5-diiodophenyl)-2-bromoacrylate 
• 1586740-71-7 (Z)-methyl 3-(2-acetamidophenyl)-2-bromoacrylate 
• 1586740-72-8 (Z)-propyl 2-bromo-3-(2-aminophenyl)acrylate 
• 1586740-73-9 (Z)-isopropyl 2-bromo-3-(2-aminophenyl)acrylate 
• 1586740-74-0 (Z)-3-(2-aminophenyl)-2-bromoacrylamide 
• 1202-04-6 indole-2-carboxylic acid methyl ester 
• 210345-56-5 5-bromo-1H-indole-2-carboxylic acid methyl ester 
• 1670-84-4 1H-indole-2-carboxamide 

Relevant articles and documents

CuI-catalyzed intramolecular cyclization of 3-(2-aminophenyl)-2- bromoacrylate: Synthesis of 2-carboxyindoles

A new approach was described for the synthesis of substituted 2-carboxyindole using 3-(2-aminophenyl)-2-bromo-acrylates through a CuI-catalyzed intramolecular coupling. The reactions were mild, rapid and with good to excellent yields.