14031-80-2

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 92-69-3 4-Phenylphenol 
• 7446-70-0 aluminium trichloride 
• 630-20-6 1,1,1,2-tetrachoroethane 
• 148-86-7 4-acetoxybiphenyl 

Downstream Products

• 81109-73-1 C₂₆H₂₅NO₂ 
• 128961-15-9 2'-hydroxy-5'-phenylchalcone 
• 128961-16-0 (E)-1-(4-Hydroxy-biphenyl-3-yl)-3-(4-methoxy-phenyl)-propenone 
• 87241-63-2 (E)-1-(4-Hydroxy-biphenyl-3-yl)-3-(4-hydroxy-3-methoxy-phenyl)-propenone 
• 51117-67-0 (E)-3-(4-Dimethylamino-phenyl)-1-(4-hydroxy-biphenyl-3-yl)-propenone 
• 84942-33-6 5-Amino-3-ethyl-biphenyl-4-ol; hydrochloride 
• 1284282-57-0 6-phenyl-2-trifluoromethylchromone 
• 58555-02-5 6-phenyl-chromen-4-one 
• 87241-61-0 (E)-1-(4-Hydroxy-biphenyl-3-yl)-3-(2-hydroxy-phenyl)-propenone 
• 27827-66-3 6-methyl-8-phenyl-3,4-dihydro-2H-benzo[b][1,5]oxazocin-3-ol 
• 199585-71-2 4-[N-Ethylsulfonyl-N-(4,4,4-Trifluorobutyl)]Amino-6-Phenyl-2,2-Dimethylchroman 
• 199585-70-1 4-(N-Ethylsulfonyl-N-Methyl)Amino-6-Phenyl-2,2-Dimethyl-Chroman 

Relevant academic research and scientific papers

Norrish Type I Photoreaction in the Presence of Phenols; an Intermolecular Photo-Fries Rearrangement

Pinacolone photolysis in the presence of phenols leads to phenyl acetates and hydroxy acetophenones; Norrish type I cleavage and subsequent hydrogen abstraction from the phenol by the tert-butyl radical gives rise to acyl-aryloxy radical pairs which recombined constituting an intermolecular photo-Fries rearrangement.