1403588-91-9Relevant articles and documents
Synthesis of β-C-Glycosyl Amino Acids by Ring Opening of Donor-Acceptor Spiro-cyclopropanecarboxylated Sugars
Ramakrishna, Bandi,Sudharani, Chalapala,Sridhar, Perali Ramu
, p. 558 - 565 (2016/07/22)
The electrophilic ring opening of donor-acceptor spiro-cyclopropanecarboxylated sugars are shown to provide easy access to the stereoselective synthesis of β-C-glycosyl D- and L-alanine derivatives. A possible mechanism is proposed for the ring-opening reaction based on the obtained crystal structure of one of the spiro-cyclic sugar moieties.