179090-11-0

Basic information

• Product Name: (3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-one
• Synonyms: (3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-one
• CAS NO: 179090-11-0
• Molecular Weight: 536.668
• Mol File: 179090-11-0.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-one(179090-11-0)
• EPA Substance Registry System: (3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-one(179090-11-0)

Safety Data

• Hazardous Substances Data: 179090-11-0(Hazardous Substances Data)

Upstream product

• 75-24-1 trimethylaluminum 
• 82598-84-3 2,3,4,6-tetra-O-benzyl-D-galactonolactone 
• 1271-66-5 dimethyltitanocene 
• 857892-47-8 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranose 
• 935666-36-7 chloromethyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside 
• 352020-72-5 3,4,5,7-tetra-O-benzyl-1-deoxy-α-D-galacto-hept-2-ulopyranose 

Downstream Products

• 1274877-88-1 C₄₇H₅₃FO₁₃ 
• 1274877-62-1 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galacto-hept-2-ulopyranosyl-(2-1)-3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-β-D-glucopyranoside 
• 1403588-87-3 (S)-methyl 2-azido-3-((2S,3S,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl) tetrahydro-2H-pyran-2-yl)-propanoate 
• 1403588-91-9 (R)-methyl 2-azido-3-((2S,3S,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)-propanoate 
• 1462962-21-5 (2R,3S,6S)-3-((tert-butyldimethylsilyl)oxy)-2-(((tert-butyldimethylsilyl)oxy)methyl)-6-((Z)-((3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-ylidene)methyl)dihydro-2H-pyran-4(3H)-one 
• 1462962-15-7 (2R,3S,6S)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-6-((Z)-((3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-ylidene)methyl)-3,6-dihydro-2H-pyran 
• 1462962-14-6 (2R,3R,6S)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-6-((Z)-((3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-ylidene)methyl)-3,6-dihydro-2H-pyran 
• 1347658-94-9 (5R)-1,3,4,5-tetra-O-benzyl-5-C-(6-fluoro-2-phenylquinolin-4-yl)-D-arabinitol 
• 1347658-91-6 (5R)-1,2,3,5-tetra-O-benzyl-5-C-(2-phenylquinolin-4-yl)-D-arabinitol 
• 1347658-92-7 (5R)-1,3,4,5-tetra-O-benzyl-5-C-[2-(4-fluorophenyl)quinolin-4-yl]-D-arabinitol 
• 190505-05-6 1-(2',3',4',6'-tetra-O-benzyl-β-D-galactopyranosyl)-2-hydroxymethyl-3-propanol 

Relevant articles and documents

Stereoselective Palladium-Catalyzed Arylation of Exo-Glycals with Aryl Iodides

A novel methodology for the arylation of exo-glycals has been developed. A range of exo-glycals underwent reactions with aryl iodides in the presence of a palladium catalyst. The transformation proceeded in a stereoselective manner to afford Z-isomers. Th

Heck-type cross-coupling between halo-exo-glycals and endo-glycals: A practical way to achieve C-glycosidic disaccharides

An effective Heck-type cross-coupling reaction between halo-exo-glycals and endo-glycals to achieve C-glycosidic disaccharides has been developed. Using Pd(OAc)2 as the catalyst, dppp as ligand and K2CO 3 as base, the reac

Sonogashira couplings of halo- and epoxy-halo-exo-glycals: Concise entry to carbohydrate-derived enynes

Furanose- and pyranose-derived mono- and dihalo-exo-glycals undergo Sonogashira coupling reactions in the presence of Pd catalysts to give carbohydrate-derived enynes in a completely stereoselective manner. On the other hand, a furanose-derived 2, 3-anhydrohalo-exo-glycal, available from D-mannose in five steps, undergoes Pd0-catalyzed Sonogashira coupling, leading to 2-deoxyenynes.