1404363-17-2

Basic information

• Product Name: (E)-1-phenoxy-4-(3,3,3-trifluoroprop-1-en-1-yl)benzene
• Synonyms: (E)-1-phenoxy-4-(3,3,3-trifluoroprop-1-en-1-yl)benzene
• CAS NO: 1404363-17-2
• Molecular Weight: 264.247
• Mol File: 1404363-17-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-1-phenoxy-4-(3,3,3-trifluoroprop-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-phenoxy-4-(3,3,3-trifluoroprop-1-en-1-yl)benzene(1404363-17-2)
• EPA Substance Registry System: (E)-1-phenoxy-4-(3,3,3-trifluoroprop-1-en-1-yl)benzene(1404363-17-2)

Safety Data

• Hazardous Substances Data: 1404363-17-2(Hazardous Substances Data)

Upstream product

• 1260111-93-0 dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate 
• 4200-06-0 1-(4-ethynylphenoxy)benzene 
• 101-55-3 4-Bromodiphenyl ether 
• 381-98-6 trifluoromethyacrylic acid 
• 1226574-99-7 (E)-diphenyl-β-(trifluoromethyl)vinylsulfonium trifluoromethanesulfonate 
• 51067-38-0 4-phenoxyphenylboronic acid 

Relevant articles and documents

Metal-Free Visible-Light-Mediated Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes in Continuous Flow

We report herein a novel photoredox-catalyzed hydrotrifluoromethylation of unsaturated systems under continuous flow. This metal-free method is easily broadened to other perfluoroalkyl groups (RF = CF3, CFCl2, CF2/su

Highly selective activation of vinyl C-S bonds over aryl C-S bonds in the Pd-catalyzed coupling of (E)-(β-trifluoromethyl)vinyldiphenylsulfonium salts: Preparation of trifluoromethylated alkenes and dienes

We describe the Suzuki coupling reaction of (E)-(β-trifluoromethyl) vinyldiphenylsulfonium salts with arylboronic acid. The highly efficient and selective reaction provides a useful and mild method for the synthesis of trifluoromethylated alkenes and dienes. Subsequent DFT studies showed that the oxidative addition transition state of the vinyl C-S bond is much more favorable (11.7 kcal mol-1) than that of the aryl C-S bond. Copyright