14051-41-3

Basic information

• Product Name: 2-propyl-
• CAS NO: 14051-41-3
• Molecular Weight: 128.171
• Mol File: 14051-41-3.mol

Chemical Properties

• CAS DataBase Reference: 2-propyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-propyl-(14051-41-3)
• EPA Substance Registry System: 2-propyl-(14051-41-3)

Safety Data

• Hazardous Substances Data: 14051-41-3(Hazardous Substances Data)

Upstream product

• 592-41-6 1-hexene 
• 124-38-9 carbon dioxide 
• 73881-10-4 (E)-1-bromo-2-hexene 
• 2497-18-9 (E)-2-hexen-1-yl acetate 

Relevant articles and documents

Activated alkyl- and allyl-alkali metal reagents: Contrasting behaviour towards ethylene

Ethylene, hex-1-ene and (+)-α-pinene were readily metallated in methylcyclohexane with the system nBuLi/LiK(OCH2CH2NMe2)2.The regioselectivity of the reaction of metallated hex-1-ene and (+)-α-pinene with CO2 could be substantially modified by the addition of Mg(OCH2CH2OEt)2.Addition of the latter also solubilizes the organometallic reagents.The allylmetallic products from the metallation of hex-1-ene and α-pinene added to ethylene under mild conditions.Whereas up to four molecules of ethylene added to metallated hex-1-ene, only one or two, depending on the reaction ratios, added to metallated α-pinene.Similar reactions involving use of a variety of other strong bases such as nBuLi/tC5H11OK and nBuM (M = Li, Na, K), with and without added TMEDA, indicated that the presence of a tertiary amine, apart from assisting the metallation reaction, is essential for the occurrence of the addition.

Ligand-controlled regiodivergent Ni-catalyzed reductive carboxylation of allyl esters with CO2

A novel Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO2 has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.

Regioselective Synthesis of β,γ-Unsaturated Acids by the Electrochemical Carboxylation of Allylic Bromides Using a Reactive-metal Anode

Electrolysis of γ-mono and disubstituted allylic bromides in the presence of atmospheric pressure of carbon dioxide using a platinum cathode and a magnesium anode gave regioselectively the corresponding γ-mono and disubstituted β,γ-unsaturated carboxylic acids in 34-71percent yields.