14064-21-2

Basic information

• Product Name: 2-FURALDEHYDE DIMETHYLHYDRAZONE
• Synonyms: 2-FURALDEHYDE DIMETHYLHYDRAZONE;FURFURAL DIMETHYL-HYDRAZONE;2-Furancarbaldehyde dimethylhydrazone;Furan-2-carbaldehyde dimethylhydrazone;2-Furaldehyde 2,2-dimethylhydr;2-Furaldehyde 2,2-dimethylhydrazone, 98%;2-Furaldehyde dimethylhydrazone 97%;DURWBNUASAZMSN-UHFFFAOYSA-N
• CAS NO: 14064-21-2
• Molecular Formula: C₇H₁₀N₂O
• Molecular Weight: 138.17
• Product Categories: Miscellaneous;API intermediates
• Mol File: 14064-21-2.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 98 °C9.5 mm Hg(lit.)
• Flash Point: 195 °F
• Appearance: /
• Density: 1.042 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0884mmHg at 25°C
• Refractive Index: n20/D 1.578(lit.)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 2-FURALDEHYDE DIMETHYLHYDRAZONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-FURALDEHYDE DIMETHYLHYDRAZONE(14064-21-2)
• EPA Substance Registry System: 2-FURALDEHYDE DIMETHYLHYDRAZONE(14064-21-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• WGK Germany: 3
• Hazardous Substances Data: 14064-21-2(Hazardous Substances Data)

Usage

Uses

2-Furaldehyde dimethylhydrazone (2-furaldehyde N,N-dimethylhydrazone) has been used in the preparation of:furyl-1,4-quinone and hydroquinones by reaction with benzo- and naphthoquinonesdimethylaminohydrazonofurylquinones

General Description

Combined matrix isolation FTIR and theoretical DFT(B3LYP)/6-311++G(d,p) study of 2-furaldehyde dimethylhydrazone has been reported.

InChI:InChI=1/C7H10N2O/c1-9(2)8-6-7-4-3-5-10-7/h3-6H,1-2H3/b8-6+

Upstream product

• 98-01-1 furfural 
• 57-14-7 N,N-Dimethylhydrazine 
• 540-73-8 1,2-Dimethylhydrazine 

Downstream Products

• 617-90-3 2-furancarbonitrile 
• 3533-63-9 dimethyl (2E)-2-(dimethylamino)but-2-enedioate 
• 303789-75-5 5-(2,4,6-trinitrophenyl)furfural N,N-dimethylhydrazone 
• 303104-21-4 2-{5-[(dimethylhydrazono)methyl]furan-2-yl}-2-hydroxy-1-phenylethanone 
• 828923-09-7 5-(1-hydroxy-2-oxo-2-phenylethyl)furan-2-carbaldehyde 
• 828923-11-1 5-(2-hydroxy-2-phenylacetyl)furan-2-carbaldehyde 
• 303095-04-7 1-{5-[(dimethylhydrazono)methyl]furan-2-yl}-2-hydroxy-2-phenylethanone 
• 1314779-69-5 [2-(dimethylamino)phenyl](furan-2-yl)methanone 
• 617-89-0 furan-2-ylmethanamine 

Relevant articles and documents

THERAPEUTIC COMPOSITION OF CURE-PRO COMPOUNDS FOR TARGETED DEGRADATION OF BET DOMAIN PROTEINS, AND METHODS OF MAKING AND USAGE

The present application is directed to a therapeutic composition, comprising two precursor compounds (monomers) that are suitable for assembly via two or more reversible covalent bonds. The monomers are polyfunctionalized molecules comprising a bioorthogo

Polyoxometalate-Driven Ease Conversion of Valuable Furfural to trans- N, N-4,5-Diaminocyclopenten-2-ones

We investigated the catalytic efficacy of silicotungstic acid (H4SiW12O40) polyoxometalate (POM) toward the reaction between furfural and amines that selectively yields trans-N,N-4,5-substituted-diaminocyclopenten-2-ones (trans-DACPs). H4SiW12O40 facilita

Chemical cascades in water for the synthesis of functionalized aromatics from furfurals

One-pot synthetic routes from furfurals to polysubstituted aromatic compounds have been developed in water, without the need for any organic solvents. The reaction proceeds via an uncatalysed, one-pot reaction cascade through formation of a hydrazone derivative, in situ cycloaddition with a dienophile, then aromatisation. A range of substituted phthalimides can be accessed with complete control over the substitution pattern. The reaction was also extended to other dienophiles and the diene 2-furylacrolein. The phthalimide products were further elaborated to produce a variety of polysubstituted benzenes including pharmaceutically relevant compounds.