1408285-51-7

Basic information

• Product Name: 4,4,5,5-tetramethyl-2-(5-(trimethylstannyl)thiophen-2-yl)-1,3,2-dioxaborolane
• Synonyms: 4,4,5,5-tetramethyl-2-(5-(trimethylstannyl)thiophen-2-yl)-1,3,2-dioxaborolane
• CAS NO: 1408285-51-7
• Molecular Weight: 372.911
• Mol File: 1408285-51-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,4,5,5-tetramethyl-2-(5-(trimethylstannyl)thiophen-2-yl)-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4,5,5-tetramethyl-2-(5-(trimethylstannyl)thiophen-2-yl)-1,3,2-dioxaborolane(1408285-51-7)
• EPA Substance Registry System: 4,4,5,5-tetramethyl-2-(5-(trimethylstannyl)thiophen-2-yl)-1,3,2-dioxaborolane(1408285-51-7)

Safety Data

• Hazardous Substances Data: 1408285-51-7(Hazardous Substances Data)

Upstream product

• 61676-62-8 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 91509-50-1 C₇H₁₁LiSSn 

Downstream Products

• 1408285-55-1 4,4,5,5-tetramethyl-2-(5-(4-nitrophenyl)thiophen-2-yl)-1,3,2-dioxaborolane 
• 1408285-58-4 C₁₇H₁₈BNO₂S 
• 1402234-05-2 4,4,5,5-tetramethyl-2-(5-(4-(trifluoromethyl)phenyl)thiophen-2-yl)-1,3,2-dioxaborolane 
• 1402240-69-0 3-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyridine 
• 1408285-62-0 1-(4-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)phenyl)ethanone 
• 459409-74-6 4,4,5,5-tetramethyl-2-(5-phenylthiophen-2-yl)-1,3,2-dioxaborolane 
• 1408285-64-2 N,N-dimethyl-4-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)aniline 
• 1402227-47-7 2-(5-(3-methoxyphenyl)thiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1408285-67-5 2-(5-(2,5-dimethoxyphenyl)thiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 886-65-7 1,4-diphenyl-1,3-butadiene 
• 239075-02-6 5,5'-di(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2,2'-bithiophene 
• 41123-26-6 2,5-di((E)-styryl)thiophene 

Relevant articles and documents

Chemoselective cross-coupling reactions with differentiation between two nucleophilic sites on a single aromatic substrate

A new thiophene building block, containing both a stannyl group and a boronic ester, was prepared. From this starting material, a general, nucleophile-selective one-pot reaction was developed, exploiting the different reactivities of the Stille and Suzuki-Miyaura cross-coupling reactions. A series of aromatic electrophiles were used to demonstrate the high functional group tolerance.