140901-74-2

Basic information

• Product Name: (+/-)-5-endo-Acetoxymethyl-2-exo-methylsulfonyloxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane
• Synonyms: (+/-)-5-endo-Acetoxymethyl-2-exo-methylsulfonyloxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane
• CAS NO: 140901-74-2
• Molecular Weight: 433.504
• Mol File: 140901-74-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-5-endo-Acetoxymethyl-2-exo-methylsulfonyloxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-5-endo-Acetoxymethyl-2-exo-methylsulfonyloxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane(140901-74-2)
• EPA Substance Registry System: (+/-)-5-endo-Acetoxymethyl-2-exo-methylsulfonyloxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane(140901-74-2)

Safety Data

• Hazardous Substances Data: 140901-74-2(Hazardous Substances Data)

Upstream product

• 140901-67-3 (+/-)-2-endo-Acetoxymethyl-7-oxabicyclo<2.2.1>hept-5-ene 
• 88517-51-5 7-oxabicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid methyl ester 
• 89898-05-5 (1RS,2SR,4RS)-7-oxabicyclo[2.2.1]hept-5-ene-2-methanol 
• 127-65-1 chloroamine-T 
• 124-63-0 methanesulfonyl chloride 
• 140901-72-0 (+/-)-5-endo-Acetoxymethyl-2-exo-hydroxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 

Downstream Products

• 140901-77-5 (+/-)-5-endo-Hydroxymethyl-2-exo-methylsulfonyloxy-3-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 

Relevant articles and documents

Synthesis of Amino-5a-carba-deoxyhexopyranoses from 2(3)-Acetoxy-5-acetoxymethyl-3(2)-p-toluenesulfonamido-7-oxabicycloheptanes

cis-Hydroxyamination of endo-2-acetoxymethyl-7-oxabicyclohept-5-ene (1) under Sharpless condition affords two positional isomers 3 and 7 of 5-endo-acetoxymethyl-2(3)-exo-hydroxy-3(2)-exo-p-toluenesulfonamido-7-oxabicycloheptanes.Cleavage of