140918-64-5Relevant academic research and scientific papers
The synthesis and applications of a micro-pine-structured nanocatalyst
Polshettiwar, Vivek,Nadagouda, Mallikarjuna N.,Varma, Rajender S.
, p. 6318 - 6320 (2008)
Dendritic nanoferrites with a micro-pine morphology have been synthesized for the first time under microwave irradiation conditions without using any reducing or capping reagent; the nanoferrites were then functionalized and coated with Pd metal, which catalyzes various organic transformations. The Royal Society of Chemistry 2008.
Highly efficient synthesis of 1,2-disubstituted acetylenes derivatives from the cross-coupling reactions of 1-bromoalkynes with organotitanium reagents
Li, Qing-Han,Wu, Chuan
supporting information, (2021/08/25)
A Highly efficient route for the synthesis of 1,2-disubstituted acetylene derivatives has been developed by nickel catalyzed cross-couplings of alkynyl halides with aryl titanium reagents under mild conditions. This has given corresponding cross-coupling products good to excellent isolated yields of up to 92 %. The aryls bearing electron-donating or electron-withdrawing groups in either alkynylhalides or aryltitanium substrates gave cross-coupling products good yields. This process was simple and easily performed, which provides an efficient method for the synthesis of 1,2-disubstituted acetylenes derivatives.
Highly efficient synthesis of 1,2-disubstituted acetylenes derivatives from the cross-coupling reactions of 1-bromoalkynes with organoalane reagents
Shao, Xue-Bei,Jiang, Xin,Li, Qing-Han,Zhao, Zhi-Gang
, p. 6063 - 6070 (2018/09/12)
A Highly efficient route for the synthesis of 1,2-disubstituted acetylene derivatives has been developed by palladium catalyzed cross-couplings of alkynyl halides with (hetero)aryl aluminium reagents under mild conditions. This has given corresponding cross-coupling products good to excellent isolated yields of up to 99%. The aryls bearing electron-donating or electron-withdrawing groups in either alkynylhalides or arylaluminum substrates gave cross-coupling products good yields. This process was simple and easily performed, which provides an efficient method for the synthesis of 1,2-disubstituted acetylenes derivatives. On the basis of the experimental results, a possible catalytic cycle has been proposed.
