14092-14-9Relevant academic research and scientific papers
Bis(β-ketoiminate) dioxo tungsten(VI) complexes as precursors for growth of WOx by aerosol-assisted chemical vapor deposition
Su, Xiaoming,Panariti, Persi,Abboud, Khalil A.,McElwee-White, Lisa
, p. 219 - 227 (2019/06/05)
Bis(β-ketoiminate) dioxo tungsten(VI) complexes WO2L2 (L = acNac, acNacMe, acNacEt) have been synthesized and characterized. The thermal behaviors and possible decomposition mechanisms of these dioxo compounds were studied by TGA, MS and thermolysis. The performance of WO2(acNacMe)2 as an AACVD precursor was evaluated at growth temperatures of 250–550 °C using nitrogen as the carrier gas. The elemental compositions of the as-deposited and sputtered tungsten oxide films were determined by XPS. The morphology and stoichiometry of the as-deposited films were studied by SEM and XRD.
2-(N-Alkylamino)-1-(trifluoroacetimidoyl)vinyl ketone derivatives as potential reagents in heterocyclic synthesis
Vasil'Ev,Prezent,Ignatenko,Dorokhov
experimental part, p. 2359 - 2363 (2010/02/16)
A reaction of 3-acetyl-4-amino-5,5,5-trifluoropent-3-en-2-one diphenylboron chelate and ammonia or primary amines affords 4-amino-or 4-alkylamino-3- trifluoroacetimidoylpent-3-en-2-ones, new reagents which can be used for the synthesis of pyrimidines with trifluoromethyl group.
