141185-70-8

Basic information

• Product Name: C₉H₁₀⁽²⁾HN
• CAS NO: 141185-70-8
• Molecular Weight: 134.185
• Mol File: 141185-70-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: C₉H₁₀⁽²⁾HN(CAS DataBase Reference)
• NIST Chemistry Reference: C₉H₁₀⁽²⁾HN(141185-70-8)
• EPA Substance Registry System: C₉H₁₀⁽²⁾HN(141185-70-8)

Safety Data

• Hazardous Substances Data: 141185-70-8(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 21175-64-4 1,1-dideuteriophenylmethanol 
• 3592-47-0 Benzaldehyde-d 
• 75-04-7 ethylamine 

Relevant articles and documents

Radical Cations from N-Alkyl Substituted Imines: an EPR Study

Following γ-radiolysis of dilute solutions of imines in trichlorofluoromethane at 77 K, EPR spectra of the corresponding radical cations were recorded.For PhCH=NEt amnd PhCH=NCHMe2 the primary 2A' cations were formed, but in each case as a mixt

Reactions of N-Chloro-N-alkylbenzylamines with Amines in Acetonitrile. Origin of Steric Effect in Imine-Forming Elimination

Reaction of N-chloro-N-alkylbenzylamines in which the alkyl group is Me, Et, i-Pr, sec-Bu, and t-Bu with MeNH2 and Et2NH in MeCN have been studied kinetically.The eliminations are quantitative and regiospecific, producing only N-benzylidenealkylamines.The relative rates of elimination for Me/Et/i-Pr/sec-Bu/t-Bu alkyl substituents are 1/0.6/0.4/0.3/0.1 with MeNH2 and 1/0.5/0.3/0.2/0.03 with Et2NH, respectively.Comparison with published data reveals that Charton's value for the imine-forming elimination decreases with the variation of the base-solvent from MeONa-MeOH to MeNH2-MeCN but increases when the base is changed from MeNH2 to Et2NH.For a given base, Hammett ρ and kH/kD values decrease and the ΔH(excit.) and ΔS(excit.) values increase with bulkier alkyl substituents.From these results, the origin of the steric effect in imine-forming elimination is attributed to the repulsive interaction between the alkyl group and the base in the transition state.