1412902-25-0

Basic information

• Product Name: dimethyl 1-(3,5-dimethylphenylsulfonyl)-3-vinyl-2,3-dihydroquinoline-4,4(1H)-dicarboxylate
• Synonyms: dimethyl 1-(3,5-dimethylphenylsulfonyl)-3-vinyl-2,3-dihydroquinoline-4,4(1H)-dicarboxylate
• CAS NO: 1412902-25-0
• Molecular Weight: 443.521
• Mol File: 1412902-25-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl 1-(3,5-dimethylphenylsulfonyl)-3-vinyl-2,3-dihydroquinoline-4,4(1H)-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 1-(3,5-dimethylphenylsulfonyl)-3-vinyl-2,3-dihydroquinoline-4,4(1H)-dicarboxylate(1412902-25-0)
• EPA Substance Registry System: dimethyl 1-(3,5-dimethylphenylsulfonyl)-3-vinyl-2,3-dihydroquinoline-4,4(1H)-dicarboxylate(1412902-25-0)

Safety Data

• Hazardous Substances Data: 1412902-25-0(Hazardous Substances Data)

Upstream product

• 1493-27-2 ortho-nitrofluorobenzene 
• 108-59-8 malonic acid dimethyl ester 
• 25260-60-0 cis-1,4-bis(acetyloxy)but-2-ene 
• 1412902-20-5 dimethyl 2-[2-(3,5-dimethylphenylsulfonamido)phenyl]malonate 
• 26465-37-2 dimethyl 2-(2-nitrophenyl)malonate 
• 86162-61-0 C₁₁H₁₃NO₄ 

Relevant articles and documents

Regio- and enantioselective synthesis of functionalized tetrahydroquinolines by palladium-catalyzed cyclization of 2- amidophenylmalonates with allylic bisacetates

A palladium-catalyzed cyclization of 2-amidophenylmalonates with allylic bisacetates is described. Tetrahydroquinolines having a vinyl group at the 3- or 2-position were produced, in which the regioselectivity of the resulting products was altered depending on the substituent on the amino group. The product was transformed to the azabicyclo[3.3.1]nonene via the ring-closing metathesis. Enantioselective reactions also successfully proceeded in the presence of (S)-BINAP to give the optically active tetrahydroquinoline with high enantioselectivity.