141355-51-3

Basic information

• Product Name: 2-Thiazolidinethione, 4-(1-methylethyl)-3-[1-oxo-4-(phenylmethoxy)butyl]-, (R)-
• CAS NO: 141355-51-3
• Molecular Formula: C17H23NO2S2
• Molecular Weight: 337.507
• Mol File: 141355-51-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Thiazolidinethione, 4-(1-methylethyl)-3-[1-oxo-4-(phenylmethoxy)butyl]-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Thiazolidinethione, 4-(1-methylethyl)-3-[1-oxo-4-(phenylmethoxy)butyl]-, (R)-(141355-51-3)
• EPA Substance Registry System: 2-Thiazolidinethione, 4-(1-methylethyl)-3-[1-oxo-4-(phenylmethoxy)butyl]-, (R)-(141355-51-3)

Safety Data

• Hazardous Substances Data: 141355-51-3(Hazardous Substances Data)

Upstream product

• 4541-14-4 4-benzyloxy-butan-1-ol 
• 10385-30-5 4-(benzyloxy)butanoic acid 
• 110199-16-1 4(R)-isopropyl-1,3-thiazolidine-2-thione 

Downstream Products

• 143091-76-3 (2S,3R)-2-(2-Benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-1-((R)-4-isopropyl-2-thioxo-thiazolidin-3-yl)-butan-1-one 
• 141355-53-5 (2S,3R)-2-(2-Benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-butyramide 
• 141355-52-4 (2S,3R)-2-(2-Benzyloxy-ethyl)-3-hydroxy-1-((R)-4-isopropyl-2-thioxo-thiazolidin-3-yl)-butan-1-one 

Relevant articles and documents

Convenient Asymmetric Synthesis of 3(S)-3--5-hydroxypyrrolidon-2-one, a Useful Synthon for the Thienamycin-like γ-Lactam

Chiral 3-substituted 5-hydroxypyrrolidin-2-one 12, useful for the synthesis of thienamycin-like γ-lactam, was successfully synthesised by utilising highly diastereoselective alkylation with the tin(II) enolate of 7 onto acetaldehyde, ammonolysis of the resultant amide 9, and oxidative cyclisation of 11.