141356-77-6

Basic information

• Product Name: Benzoic acid, 4-chloro-, 2-hydroxyheptyl ester, (S)-
• CAS NO: 141356-77-6
• Molecular Formula: C14H19ClO3
• Molecular Weight: 270.756
• Mol File: 141356-77-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-chloro-, 2-hydroxyheptyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-chloro-, 2-hydroxyheptyl ester, (S)-(141356-77-6)
• EPA Substance Registry System: Benzoic acid, 4-chloro-, 2-hydroxyheptyl ester, (S)-(141356-77-6)

Safety Data

• Hazardous Substances Data: 141356-77-6(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 74-11-3 para-chlorobenzoic acid 
• 693-02-7 hex-1-yne 
• 141339-93-7 t-butyl 2-chloro-3-oxooctanoate 
• 15163-60-7 p-chlorobenzoic acid potassium salt 
• 66720-07-8 tert-butyl 3-oxooctanoate 
• 41055-92-9 1-chloro-2-heptanone 
• 141339-60-8 4-Chloro-benzoic acid 2-oxo-heptyl ester 

Relevant articles and documents

Asymmetric hydroformylation of Z -Enamides and enol esters with rhodium-bisdiazaphos catalysts

Asymmetric hydroformylation (AHF) of Z-enamides and Z-enol esters provides chiral, alpha-functionalized aldehydes with high selectivity and atom economy. Rh-bisdiazaphospholane catalysts enable hydroformylation of these challenging disubstituted substrates under mild reaction conditions and low catalyst loadings. The synthesis of a protected analog of l-DOPA demonstrates the utility of AHF for enantioselective, atom-efficient synthesis of peptide precursors.