1414261-80-5Relevant academic research and scientific papers
Synthesis of diarylmethanes via metal-free reductive cross-coupling of diarylborinic acids with tosyl hydrazones
Li, Xijing,Feng, Yuanyuan,Lin, Lin,Zou, Gang
, p. 10991 - 10995 (2013/02/22)
This paper describes a practical and efficient procedure that takes advantage of diarylborinic acids as a cost-effective alternative to arylboronic acids for synthesis of diarylmethanes through metal-free reductive cross-coupling with N-tosylhydrazones of aromatic aldehydes and ketones. The procedure tolerates hydroxyl, halide, amine, and allyl functionality, complementary to the transition-metal catalyzed cross-coupling techniques.
Influence of lewis acid and solvent in the hydrosiylation of aldehydes and ketones with Et3SiH; Tris(pentafluorophenyl)borane B(C 6F5)3 versus Metal inflates [M(OTf) 3; M = Sc, Bi, Ga, and Al] - Mecha
Bach, Peter,Albright, Andrea,Laali, Kenneth K.
experimental part, p. 1961 - 1966 (2009/09/06)
The scope of the B(C6F5)3-catalyzed hydrosilylation of (X)Ph- CH=O and (X)Ph-C(R)=O was expanded to include a large set of subslitulents (X =H, p-Me, o-Me, p-F, o-F, p-Cl, p-Br, p-NO2m, m-NO2, p-Et; R
