1415919-35-5Relevant academic research and scientific papers
Hydrogenation of silyl formates: sustainable production of silanol and methanol from hydrosilane and carbon dioxide
Koo, Jangwoo,Kim, Seung Hyo,Hong, Soon Hyeok
supporting information, p. 4995 - 4998 (2018/05/23)
A new process for simultaneously obtaining two chemical building blocks, methanol and silanol, was realized starting from silyl formates which can be derived from silane and carbon dioxide. Understanding the reaction mechanism enabled us to improve the reaction efficiency by the addition of a small amount of methanol.
Catalytic synthesis of silyl formates with 1 atm of CO2 and their utilization for synthesis of formyl compounds and formic acid
Itagaki, Shintaro,Yamaguchi, Kazuya,Mizuno, Noritaka
, p. 347 - 352 (2013/02/22)
In the presence of simple Rh2(OAc)4 and K 2CO3, the hydrosilylation of CO2 (1 atm) with various hydrosilanes efficiently proceeded to afford the corresponding silyl formates in moderate to high yields (53-90% yields). By using the dimethylphenylsilyl formate produced by the hydrosilylation, formamides, formic acid, and a secondary alcohol (via an aldehyde) could be synthesized by the reaction with various nucleophilic reagents such as amines, aniline, water, and the Grignard reagent.
