14181-72-7

Basic information

• Product Name: 2-BROMO-1-PHENYL-1-ETHANONE OXIME
• Synonyms: 2-BROMO-1-PHENYL-1-ETHANONE OXIME;2-BroMo-1-phenylethanone oxiMe
• CAS NO: 14181-72-7
• Molecular Formula: C₈H₈BrNO
• Molecular Weight: 214.06
• Mol File: 14181-72-7.mol
• Article Data: 13

Chemical Properties

• Melting Point: 97-100
• Boiling Point: 296.8°Cat760mmHg
• Flash Point: 133.3°C
• Appearance: /
• Density: 1.45g/cm³
• Vapor Pressure: 0.00063mmHg at 25°C
• Refractive Index: 1.57
• CAS DataBase Reference: 2-BROMO-1-PHENYL-1-ETHANONE OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BROMO-1-PHENYL-1-ETHANONE OXIME(14181-72-7)
• EPA Substance Registry System: 2-BROMO-1-PHENYL-1-ETHANONE OXIME(14181-72-7)

Safety Data

• Hazard Codes: C
• Statements: R34:Causes burns.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36/37/39:Wear suitabl
• Hazardous Substances Data: 14181-72-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H8BrNO/c9-6-8(10-11)7-4-2-1-3-5-7/h1-5,11H,6H2/b10-8+

Upstream product

• 546-88-3 acetylhydroxamic acid 
• 70-11-1 α-bromoacetophenone 
• 2142-69-0 2-bromophenyl methyl ketone 
• 98-86-2 acetophenone 

Downstream Products

• 100372-82-5 3-(β-hydroxyimino-phenethyl)-pentane-2,4-dione 
• 29441-70-1 9a-morpholin-4-yl-3-phenyl-4,4a,5,6,7,8,9,9a-octahydro-cyclohepta[e][1,2]oxazine 
• 34277-21-9 1-[2-(2-chloro-phenothiazin-10-yl)-2-oxo-ethyl]-4-(2-hydroxy-ethyl)-1,4-bis-(2-hydroxyimino-2-phenyl-ethyl)-piperazinediium; dibromide 
• 34277-22-0 1-[2-(2-chloro-phenothiazin-10-yl)-2-oxo-ethyl]-1,4-bis-(2-hydroxyimino-2-phenyl-ethyl)-4-(2-hydroxy-propyl)-piperazinediium; dibromide 
• 34277-23-1 1-benzyl-4-[3-(2-chloro-phenothiazin-10-yl)-propyl]-1,4-bis-(2-hydroxyimino-2-phenyl-ethyl)-piperazinediium; dibromide 
• 32845-31-1 1-[3-(2-chloro-phenothiazin-10-yl)-2-methyl-propyl]-4-(2-hydroxy-ethyl)-1,4-bis-(2-hydroxyimino-2-phenyl-ethyl)-piperazinediium; dibromide 
• 34277-25-3 1-[2-(2-chloro-phenothiazin-10-yl)-1-methyl-ethyl]-1,4-bis-(2-hydroxyimino-2-phenyl-ethyl)-4-[2-(3,4,5-trimethoxy-benzoyloxy)-ethyl]-piperazinediium; dibromide 
• 34277-27-5 1-[3-(2-chloro-phenothiazin-10-yl)-propyl]-1,4-bis-(2-hydroxyimino-2-phenyl-ethyl)-4-[2-(3,4,5-trimethoxy-benzoyloxy)-propyl]-piperazinediium; dibromide 
• 79379-53-6 5-Ethyl-6-morpholin-4-yl-3-phenyl-5,6-dihydro-4H-[1,2]oxazine 
• 79379-55-8 5-Methyl-6-morpholin-4-yl-3,6-diphenyl-5,6-dihydro-4H-[1,2]oxazine 
• 107182-86-5 (Z)-α-(1,2,3,4-Tetrahydro-2-isochinolyl)-acetophenonoxim 
• 16451-77-7 (E)-α-(1,2,3,4-Tetrahydro-2-isochinolyl)-acetophenonoxim 
• 79379-48-9 4,5-dihydro-2-phenylcyclopentapyrrole 
• 132868-23-6 3,6-Diphenyl-6-trimethylsilanyloxy-5,6-dihydro-4H-[1,2]oxazine 

Relevant articles and documents

α-Nitrosostyrenes as Three-Atom Units for the (3+1) Cyclization Reaction: Facile Access to 2,3-Dihydrodiazete N-Oxides and Their Diversified Synthetic Conversions

An unprecedented (3+1) cyclization of α-nitrosostyrenes, generated in situ from α-bromooximes, and N-tosyloxycarbamates was developed, which enables the synthesis of a range of structurally unique and hitherto unexplored 2,3-dihydrodiazete N-oxides in mod

An efficient synthesis of 2-isoxazolines from α-haloketone oximes and dimethyl sulfonium salts

2-Isoxazolines were synthesized efficiently from a formal [4+1] cycloaddition of nitrosoalkenes and sulfur ylides, which were generated in situ from α-haloketone oximes and dimethyl sulfonium salts. This approach provides a new method to synthesize a rang

Synthesis and Beckmann rearrangement of novel (Z)-2-organylselanyl ketoximes: promising agents against grapevine anthracnose infection

We present here the synthesis of novel (Z)-2-organylselanyl ketoximes by nucleophilic substitution reaction of E/Z mixtures of 2-bromo ketoximes with nucleophilic species of selenium, which were generated in situ by simple cleavage of diorganyl diselenides with NaBH4using ethanol/THF as solvent. The new 2-organylselanyl ketoximes were synthesized in moderate to good yields and with selectivity for the (Z)-configuration. The synthesized (Z)-2-arylselanylacetophenone oximes were submitted to the Beckmann rearrangement, furnishing the corresponding N-aryl-2-(selanyl)acetamides. (Z)-1-Phenyl-2-(phenylselanyl) ketoxime has antifungal activity against Sphaceloma ampelinum and a good level of antioxidant activity in vitro in DPPH, ABTS, FRAP and lipid peroxidation assays.