141850-65-9Relevant articles and documents
Access to Unstabilized Secondary Vinylphosphines by Chemoselective Reduction of Vinylphosphinates or by P-Alkylation of the Primary Vinylphosphine
Gaumont, A. C.,Morise, X.,Denis, J. M.
, p. 4292 - 4295 (1992)
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Efficient Synthesis of Unstabilized Phospha-alkenes by Stereoselective Lewis Base-Induced Rearragement of Vinylphosphines
Gaumont, A.C.,Guillemin, J.C.,Denis, J.M.
, p. 171 - 174 (2007/10/02)
Vinylphosphines are synthesized by reduction of the corresponding vinyl-phosphonic or phosphonic esters and by P-alkylation of the vinylphosphine parent compound 1.They rearrange into phospha-alkenes in the presence of a catalytic amount of a strong Lewis