141850-65-9Relevant academic research and scientific papers
B(C6F5)3-catalyzed silylation versus reduction of phosphonic and phosphinic esters with hydrosilanes
Denis, Jean-Marc,Forintos, Henrietta,Szelke, Helga,Keglevich, Gy?rgy
, p. 5569 - 5571 (2002)
HSiR3/cat-B(C6F)3 induced dealkylation or reduction of esters of phosphorus at 20°C. A specific conversion to silylesters occurred by reaction with tertiary silanes. In contrast, free phosphines were observed in the reaction with mono- or disubstituted silanes. A mechanism was proposed to rationalize these results.
Efficient Synthesis of Unstabilized Phospha-alkenes by Stereoselective Lewis Base-Induced Rearragement of Vinylphosphines
Gaumont, A.C.,Guillemin, J.C.,Denis, J.M.
, p. 171 - 174 (2007/10/02)
Vinylphosphines are synthesized by reduction of the corresponding vinyl-phosphonic or phosphonic esters and by P-alkylation of the vinylphosphine parent compound 1.They rearrange into phospha-alkenes in the presence of a catalytic amount of a strong Lewis
