Tetrahedron Letters p. 5569 - 5571 (2002)
Update date:2022-08-17
Topics:
Denis, Jean-Marc
Forintos, Henrietta
Szelke, Helga
Keglevich, Gy?rgy
HSiR3/cat-B(C6F)3 induced dealkylation or reduction of esters of phosphorus at 20°C. A specific conversion to silylesters occurred by reaction with tertiary silanes. In contrast, free phosphines were observed in the reaction with mono- or disubstituted silanes. A mechanism was proposed to rationalize these results.
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