141885-92-9

Upstream product

• 132074-44-3 (S)-3-hydroxy-2-methylpropyl acetate 
• 98-88-4 benzoyl chloride 
• 769-78-8 vinyl benzoate 
• 141978-59-8 (R)-1-O-benzoyl-2-methylpropane-1,3-diol 
• 75-36-5 acetyl chloride 
• 112057-72-4 (RS)-1-benzoyloxy-2-methylpropan-3-ol 

Relevant academic research and scientific papers

Desymmetrization of meso 1,3- and 1,4-diols with a dinuclear zinc asymmetric catalyst

A dinuclear asymmetric zinc catalyst generated by mixing a 2:1 ratio of diethylzinc and 2,6-bis[5-2-diarylhydroxy methyl-1-pyrrolidinyl]-4-methylphenol has been contrasted with enzymes for the desymmetrization of some meso diols. The best ligand has a p-b

Lipase-based HPLC stationary phase: Enantioselective synthesis of 2- substituted 1,3-propanediol monoacetates

Pseudomonas cepacia lipase (PCL) has been immobilized by coating the enzyme on an epoxysilica HPLC column. The biocatalyst has been successfully used for the preparation of both the enantiomers of 3-acetoxy-2-benzyl- propan-1-ol and of 3-acetoxy-2-methylpropan-1-ol. The immobilized enzyme is active after months of use either in aqueous or in organic media. (C) 1999 Elsevier Science Ltd.

Enantioselective transesterification of 2-methyl-1,3-propanediol derivatives catalyzed by Pseudomonas fluorescens lipase in an organic solvent

The irreversible transesterification of racemic 2-methyl-1,3-propanediol derivatives, the monoethers 3a, 3b, 5a, and the monobenzoate 5b, with vinyl acetate catalyzed by Pseudomonas fluorescens lipase in chloroform affords enantiomerically pure chiral synthons.