14193-32-9

Upstream product

• 53081-86-0 α-(7-Brom-bicyclo<4.1.0>hept-7-yl)-benzylalkohol 
• 3282-32-4 2-diazo-acetophenone 
• 110-83-8 cyclohexene 
• 100-52-7 benzaldehyde 
• 87874-53-1 7-exo-bromo-7-endo-benzoylbicyclo<4.1.0>heptane 
• 53081-86-0 7-exo-bromo-7-endo-(α-hydroxybenzyl)bicyclo<4.1.0>heptane 
• 2415-79-4 7,7-dibromonorcarane 

Downstream Products

• 119637-20-6 2-(2'-Bromocyclohexyl)-1,1-diphenylethylene 
• 119612-37-2 4-(2'-Bromocyclohexyl)-3-phenylbutadiene 
• 119612-36-1 2-(2'-Iodocyclohexyl)-1-methyl-1-phenylethylene 
• 119612-42-9 3-(2'-Iodocyclohexyl)-2-hydroxy-2-phenylpropane 

Relevant academic research and scientific papers

Reactions of α-Diazoketones with Olefinic Compounds in Presence of Catalysts and Related Studies

A relatively stable cyclopropane adduct is produced by trapping ketocarbenes in olefin.The reactivities of ketocarbenes prepared thermally from different α-diazoketones and of the olefin substrates, and the effect of different catalysts and solvents are some of the parameters which have a pronounced effect on the yield of the products.Besides the cyclopropane adducts some side products have also been isolated and characterized.