142071-82-7

Basic information

• Product Name: 3-benzoylpyrrolo[2,1-c][1,4]benzoxazine-1,2,4-trione
• Synonyms: 3-benzoylpyrrolo[2,1-c][1,4]benzoxazine-1,2,4-trione
• CAS NO: 142071-82-7
• Molecular Weight: 319.273
• Mol File: 142071-82-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-benzoylpyrrolo[2,1-c][1,4]benzoxazine-1,2,4-trione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-benzoylpyrrolo[2,1-c][1,4]benzoxazine-1,2,4-trione(142071-82-7)
• EPA Substance Registry System: 3-benzoylpyrrolo[2,1-c][1,4]benzoxazine-1,2,4-trione(142071-82-7)

Safety Data

• Hazardous Substances Data: 142071-82-7(Hazardous Substances Data)

Upstream product

• 32781-12-7 (Z)-3-(2-oxo-2-phenylethylidene)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one 
• 79-37-8 oxalyl dichloride 
• 55135-04-1 3-Phenacylidene-3,4-dihydro-2H-1,4-benzoxazin-2-one 
• 95-55-6 2-amino-phenol 
• 5817-92-5 2,4-dioxo-4-phenylbutanoic acid 

Downstream Products

• 1125566-40-6 isopropyl 3-benzoyl-4-hydroxy-1-(o-hydroxyphenyl)-5-oxo-2,5-dihydro-1H-pyrrolo-2-spiro-3'-(2-oxo-5-(3-pyridyl)-2,3-dihydro-1H-pyrrole-4-carboxylate) 
• 1125566-28-0 ethyl 3-benzoyl-4-hydroxy-1-(o-hydroxyphenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2-spiro-3'-(5-methyl-2-oxo-1-phenyl-2,3-dihydro-1H-pyrrole-4-carboxylate) 
• 1125566-34-8 ethyl 3-benzoyl-4-hydroxy-1-(o-hydroxyphenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2-spiro-3'-(5-methyl-1-(p-methoxyphenyl)-2-oxo-2,3-dihydro-1H-pyrrole-4-carboxylate) 
• 1125566-37-1 ethyl 3-benzoyl-4-hydroxy-1-(o-hydroxyphenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2-spiro-3'-(5-methyl-1-(p-chlorophenyl)-2-oxo-2,3-dihydro-1H-pyrrole-4-carboxylate) 
• 1125566-27-9 ethyl 3-benzoyl-4-hydroxy-1-(o-hydroxyphenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2-spiro-3'-(5-methyl-2-oxo-2,3-dihydro-1H-pyrrole-4-carboxylate) 
• 1125566-31-5 ethyl 3-benzoyl-4-hydroxy-1-(o-hydroxyphenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2-spiro-3'-(5-methyl-2-oxo-1-(p-tolyl)-2,3-dihydro-1H-pyrrole-4-carboxylate) 
• 1116686-42-0 4,9-dibenzoyl-7-benzyl-3-hydroxy-1-(2-hydroxyphenyl)-8-phenyl-1,7-diazaspiro[4.4]nona-3,8-diene-2,6-dione 
• 1116686-34-0 9-acetyl-4-benzoyl-7-(4-chlorophenyl)-3-hydroxy-1-(2-hydroxyphenyl)-8-methyl-1,7-diazaspiro[4.4]nona-3,8-diene-2,6-dione 
• 1116686-39-5 9-acetyl-4-benzoyl-7-(4-bromophenyl)-3-hydroxy-1-(2-hydroxyphenyl)-8-methyl-1,7-diazaspiro[4.4]nona-3,8-diene-2,6-dione 
• 1132776-67-0 N-[3'-benzoyl-4'-hydroxy-1'-(2-hydroxyphenyl)-6,6-dimethyl-2,4,5'-trioxo-1',4,5,5',6,7-hexahydrospiro[indole-3,2'-pyrrol]-1(2H)-yl]-3-nitrobenzamide 
• 1137860-78-6 methyl 4,9-dibenzoyl-3-hydroxy-1-(2-hydroxyphenyl)-2,6-dioxo-7-phenyl-1,7-diazaspiro[4.4]nona-3,8-diene-8-carboxylate 
• 1239902-47-6 3-[4-oxo-6-phenyl-3-cyclohexyl-2-(cyclohexylimino)-3,4-dihydro-2H-1,3-oxazin-5-yl]-2H-benzo[b][1,4]oxazin-2-one 
• 1422584-58-4 3′-benzoyl-4′-hydroxy-1′-(2-hydroxyphenyl)-6,6-dimethyl-6,7-dihydrospiro[1-benzofuran-3,2′-pyrrole]-2,4,5′(1′H,5H)-trione 

Relevant articles and documents

Five-membered 2,3-dioxo heterocycles: XCVIII.* [4 + 2]-cycloaddition of alkyl vinyl ethers to 3-aroyl-1H-pyrrolo[2,1-c][1,4]benzoxazine-1,2,4- triones. A new synthetic approach to heteroanalogs of 13(14→8)-abeo steroids

3-Aroyl-1H-pyrrolo[2,1-c][1,4]benzoxazine-1,2,4-triones reacted with alkyl vinyl ethers according to the [4 + 2]-cycloaddition pattern with formation of substituted (1S*,16R*)- and (1R*,16R*)-16-alkoxy-14- aryl-3,15-dioxa-10-azatetracyclo[8.7.0.01,13.04,9

FIVE-MEMBERED 2,3-DIOXOHETEROCYCLES. XXXIII. SYNTHESIS OF 3-AROYL-1,2-DIHYDRO-4H-PYRROLOBENZOXAZINE-1,2,4-TRIONES AND THEIR REACTION WITH WATER AND ALCOHOLS

3-Aroyl-1,2-dihydro-4H-pyrrolobenzoxazine-1,2,4-triones, obtained from 3-phenacylidene-3,4-dihydro-2H-1,4-benzoxazin-2-ones and oxalyl chloride, react with water and alcohols with the formation of 2,3a-dihydroxy- and 3a-alkoxy-2-hydroxy-3-aroyl-3a,4-dihydro-1H-pyrrolobenzoxazine-1,4-diones.