1422444-54-9Relevant academic research and scientific papers
Copper-Catalyzed Tandem O-Vinylation of Arylhydroxylamines/[3,3]-Rearrangement/Cyclization: Synthesis of Highly Substituted Indoles and Benzoindoles
Yuan, Hairui,Guo, Lirong,Liu, Fengting,Miao, Zechen,Feng, Lei,Gao, Hongyin
, p. 3906 - 3912 (2019/04/25)
Herein, we developed a copper-catalyzed O-vinylation of arylhydroxylamine using vinyliodonium salts as vinylation reagents to generate a transient O-vinyl-N-arylhydroxylamine that rapidly undergoes a [3,3]-sigmatropic rearrangement and subsequent cyclizat
PhI(OAc)2-mediated oxidative trifluoromethylation of arenes with CF3SiMe3 under metal-free conditions
Wu, Xinyue,Chu, Lingling,Qing, Feng-Ling
supporting information, p. 249 - 251 (2013/02/22)
A PhI(OAc)2-mediated oxidative trifluoromethylation of arenes with CF3SiMe3 under metal-free conditions has been described. This protocol precludes the need of substrate pre-functionalization and metal catalysts, enabling
